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503 reactions imported from Wikipedia named-reactions and Organic Syntheses archives. Filter by source or search by name + summary.

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Equation Name Summary Source
1,2-Wittig rearrangement Olefination A 1,2-Wittig rearrangement is a categorization of chemical reactions in organic chemistry, and consists of a 1,2-rearrangement of an ether with an alkyllithium compound. The reaction is named for Nobe… Wikipedia: Category:Name reactions
2,3-Wittig rearrangement Olefination The [2,3]-Wittig rearrangement is the transformation of an allylic ether into a homoallylic alcohol via a concerted, pericyclic process. Because the reaction is concerted, it exhibits a high degree of… Wikipedia: Category:Name reactions
Abramov reaction The Abramov reaction is the related conversions of trialkyl to α-hydroxy phosphonates by the addition to carbonyl compounds. In terms of mechanism, the reaction involves attack of the nucleophilic ph… Wikipedia: Category:Name reactions
Achmatowicz reaction The Achmatowicz reaction, also known as the Achmatowicz rearrangement or the Achmatowicz oxidation, is an organic synthesis in which a furan is converted to a dihydropyran. In the original publication… Wikipedia: Category:Name reactions
Adams decarboxylation The Adams decarboxylation is a chemical reaction that involved the decarboxylation of coumarins which have carboxylic acid group in the third position. The decarboxylation is achieved by aqueous solut… Wikipedia: Category:Name reactions
Adkins–Peterson reaction The Adkins–Peterson reaction is the air oxidation of methanol to formaldehyde with metal oxide catalysts such as iron oxide, molybdenum trioxide or combinations thereof. Wikipedia: Category:Name reactions
Akabori amino-acid reaction There are several Akabori amino acid reactions, which are named after Shirō Akabori (Japanese: 赤堀 四郎) (1900–1992), a Japanese chemist. Wikipedia: Category:Name reactions
Albright–Goldman oxidation Oxidation The Albright–Goldman oxidation is a name reaction of organic chemistry, first described by the American chemists J. Donald Albright and Leon Goldman in 1965. The reaction is particularly suitable for … Wikipedia: Category:Name reactions
Aldol–Tishchenko reaction Condensation The Aldol–Tishchenko reaction is a tandem reaction involving an aldol reaction and a Tishchenko reaction. In organic synthesis, it is a method to convert aldehydes and ketones into 1,3-hydroxyl compou… Wikipedia: Category:Name reactions
Algar–Flynn–Oyamada reaction The Algar–Flynn–Oyamada reaction is a chemical reaction whereby a chalcone undergoes an oxidative cyclization to form a flavonol. Wikipedia: Category:Name reactions
Allan–Robinson reaction Cyclization The Allan–Robinson reaction is the chemical reaction of o-hydroxyaryl ketones with aromatic anhydrides to form flavones (or isoflavones). Wikipedia: Category:Name reactions
Allen–Millar–Trippett rearrangement Rearrangement The Allen–Millar–Trippett rearrangement is a ring expansion reaction in which a cyclic phosphine is transformed into a cyclic phosphine oxide. This name reaction, first reported in the 1960s by David … Wikipedia: Category:Name reactions
Amadori rearrangement Rearrangement The Amadori rearrangement is an organic reaction describing the acid or base catalyzed isomerization or rearrangement reaction of the N-glycoside of an aldose or the glycosylamine to the corresponding… Wikipedia: Category:Name reactions
Andrussow process The Andrussow process is the dominant industrial process for the production of hydrogen cyanide. It involves the reaction of methane, ammonia, and oxygen. The process is catalyzed by a platinum-rhodi… Wikipedia: Category:Name reactions
Angeli–Rimini reaction The Angeli–Rimini reaction is an organic reaction between an aldehyde and N-hydroxybenzenesulfonamide in presence of base forming a hydroxamic acid. Wikipedia: Category:Name reactions
Appel reaction Substitution The Appel reaction is an organic reaction that converts an alcohol into an alkyl chloride using triphenylphosphine and carbon tetrachloride. The use of carbon tetrabromide or bromine as a halide sourc… Wikipedia: Category:Name reactions
Arens–van Dorp synthesis The Arens–van Dorp synthesis is a name reaction in organic chemistry. It describes the addition of lithiated ethoxyacetylenes to ketones to give propargyl alcohols, which can undergo further reaction … Wikipedia: Category:Name reactions
Arndt–Eistert reaction In organic chemistry, the Arndt–Eistert reaction is the conversion of a carboxylic acid to its homologue. It is named for the German chemists Fritz Arndt (1885–1969) and Bernd Eistert (1902–1978). The… Wikipedia: Category:Name reactions
Asinger reaction The Asinger reaction (sometimes referred to as the Asinger-4 component reaction or A-4CR for short) is a multicomponent reaction for the synthesis of 3-thiazolines and other related heterocycles. It i… Wikipedia: Category:Name reactions
Aston–Greenburg rearrangement Rearrangement The Aston–Greenburg rearrangement is a name reaction in organic chemistry. It allows for the generation of tertiary α-alkylesters from corresponding α-haloketones through a 1,2-rearrangement, with the… Wikipedia: Category:Name reactions
Atherton–Todd reaction The Atherton-Todd reaction is a name reaction in organic chemistry, which goes back to the British chemists F. R. Atherton, H. T. Openshaw and A. R. Todd. These described the reaction for the first ti… Wikipedia: Category:Name reactions
Auwers synthesis The Auwers synthesis is a series of organic reactions forming a flavonol from a coumarone. This reaction was first reported by Karl von Auwers in 1908. Wikipedia: Category:Name reactions
Aza-Baylis–Hillman reaction The aza-Baylis–Hillman reaction or aza-BH reaction in organic chemistry is a variation of the Baylis–Hillman reaction and describes the reaction of an electron deficient alkene, usually an α,β-unsatur… Wikipedia: Category:Name reactions
Aza-Cope rearrangement Rearrangement Rearrangements, especially those that can participate in cascade reactions, such as the aza-Cope rearrangements, are of high practical as well as conceptual importance in organic chemistry, due to the… Wikipedia: Category:Name reactions
Aza-Diels–Alder reaction The aza-Diels–Alder reaction is a modification of the Diels–Alder reaction wherein a nitrogen replaces sp2 carbon. The nitrogen atom can be part of the diene or the dienophile. Wikipedia: Category:Name reactions
Aza-Wittig reaction Olefination The Aza-Wittig reaction or is a chemical reaction of a carbonyl group with an aza-ylide, also known as an iminophosphorane (R3P=NR'). Aza-Wittig reactions are most commonly used to convert aldehydes… Wikipedia: Category:Name reactions
Azide-alkyne Huisgen cycloaddition Cycloaddition The azide-alkyne Huisgen cycloaddition is a 1,3-dipolar cycloaddition between an azide and a terminal or internal alkyne to give a 1,2,3-triazole. Rolf Huisgen was the first to understand the scope of… Wikipedia: Category:Name reactions
Babler oxidation Oxidation The Babler oxidation, also known as the Babler–Dauben oxidation, is an organic reaction for the oxidative transposition of tertiary allylic alcohols to enones using pyridinium chlorochromate (PCC): Wikipedia: Category:Name reactions
Baeyer–Drewsen indigo synthesis The Baeyer–Drewsen indigo synthesis (1882) is an organic reaction in which indigo is prepared from 2-nitrobenzaldehyde and acetone The reaction was developed by von Baeyer and Viggo Drewsen in … Wikipedia: Category:Name reactions
Baeyer–Emmerling indole synthesis Baeyer–Emmerling indole synthesis is a method for synthesizing indole from a (substituted) ortho-nitrocinnamic acid and iron powder in strongly basic solution. This reaction was discovered by Adolf vo… Wikipedia: Category:Name reactions
Baeyer–Villiger oxidation Oxidation The Baeyer–Villiger oxidation is an organic reaction that forms an ester from a ketone or a lactone from a cyclic ketone, using peroxyacids or peroxides as the oxidant. The reaction is named after Ado… Wikipedia: Category:Name reactions
Bailey peptide synthesis The Bailey peptide synthesis is a name reaction in organic chemistry developed 1949 by J. L. Bailey. It is a method for the synthesis of a peptide from α-amino acid-N-carboxylic acid anhydrides (NCAs)… Wikipedia: Category:Name reactions
Baker–Venkataraman rearrangement Rearrangement The Baker–Venkataraman rearrangement is the chemical reaction of 2-acetoxyacetophenones with base to form 1,3-diketones. Wikipedia: Category:Name reactions
Balz–Schiemann reaction The Balz–Schiemann reaction (also called the Schiemann reaction) is a chemical reaction in which an aryl diazonium salt is transformed to an aryl fluoride. This reaction is a traditional route to fluo… Wikipedia: Category:Name reactions
Bamberger rearrangement Rearrangement The Bamberger rearrangement is the chemical reaction of phenylhydroxylamines with strong aqueous acid, which will rearrange to give 4-aminophenols. It is named for the German chemist Eugen Bamberger (… Wikipedia: Category:Name reactions
Bamberger triazine synthesis The Bamberger triazine synthesis in organic chemistry is a classic organic synthesis of a triazine first reported by Eugen Bamberger in 1892. Wikipedia: Category:Name reactions
Bamford–Stevens reaction The Bamford–Stevens reaction is a chemical reaction whereby treatment of tosylhydrazones with strong base gives alkenes. It is named for the British chemist William Randall Bamford and the Scottish ch… Wikipedia: Category:Name reactions
Banert cascade The Banert cascade is an organic reaction in which an NH-1,2,3-triazole is prepared from a propargyl halide or sulfate and sodium azide in a dioxane- water mixture at elevated temperatures. It is name… Wikipedia: Category:Name reactions
Barbier reaction Organometallic addition The Barbier reaction is an organometallic reaction between an alkyl halide (chloride, bromide, iodide), a carbonyl group and a metal. The reaction can be performed using magnesium, aluminium, zinc, in… Wikipedia: Category:Name reactions
Barbier–Wieland degradation Organometallic addition The Barbier–Wieland degradation is a procedure for shortening the carbon chain of a carboxylic acid by one carbon. It only works when the carbon adjacent to the carboxyl is a simple methylene bridge (… Wikipedia: Category:Name reactions
Bargellini reaction The Bargellini reaction is a chemical reaction discovered in 1906 by Italian chemist Guido Bargellini. The original reaction was a mixture of the reagents phenol, chloroform, and acetone in the presen… Wikipedia: Category:Name reactions
Bartoli indole synthesis The Bartoli indole synthesis (also called the Bartoli reaction) is the chemical reaction of ortho-substituted nitroarenes and nitrosoarenes with vinyl Grignard reagents to form substituted indoles. Wikipedia: Category:Name reactions
Barton decarboxylation The Barton decarboxylation is a radical reaction in which a carboxylic acid is converted to a thiohydroxamate ester (commonly referred to as a Barton ester). The product is then heated in the presenc… Wikipedia: Category:Name reactions
Barton–Kellogg reaction The Barton–Kellogg reaction is a coupling reaction between a diazo compound and a thioketone, giving an alkene by way of an episulfide intermediate.[1][2][3] The Barton–Kellogg reaction is also known… Wikipedia: Category:Name reactions
Barton–McCombie deoxygenation The Barton–McCombie deoxygenation is an organic reaction in which a hydroxy functional group in an organic compound is replaced by a hydrogen to give an alkyl group. It is named after British chemists… Wikipedia: Category:Name reactions
Barton nitrite ester reaction The Barton reaction, also known as the Barton nitrite ester reaction, is a photochemical reaction that involves the photolysis of an alkyl nitrite to form a δ-nitroso alcohol. Wikipedia: Category:Name reactions
Barton–Zard reaction The Barton–Zard reaction is a route to pyrrole derivatives via the reaction of a nitroalkene with an α-isocyanide under basic conditions. It is named after Derek Barton and Samir Zard who first report… Wikipedia: Category:Name reactions
Baudisch reaction In organic chemistry, the Baudisch reaction is a process for the synthesis of nitrosophenols using metal ions. Although the products are of limited value, the reaction is of historical interest as an … Wikipedia: Category:Name reactions
Baylis–Hillman reaction In organic chemistry, the Baylis–Hillman, Morita–Baylis–Hillman, or MBH reaction is a carbon–carbon bond-forming reaction between an activated alkene and a carbon electrophile in the presence of a nuc… Wikipedia: Category:Name reactions
Bechamp reaction In organic synthesis the Béchamp reaction is used for producing arsonic acids from activated aromatic substrates. The reaction is an electrophilic aromatic substitution, using arsenic acid as the elec… Wikipedia: Category:Name reactions

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