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15 reactions imported from Wikipedia named-reactions and Organic Syntheses archives. Filter by source or search by name + summary.

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Equation Name Summary Source
1,2-Wittig rearrangement Olefination A 1,2-Wittig rearrangement is a categorization of chemical reactions in organic chemistry, and consists of a 1,2-rearrangement of an ether with an alkyllithium compound. The reaction is named for Nobe… Wikipedia: Category:Name reactions
2,3-Wittig rearrangement Olefination The [2,3]-Wittig rearrangement is the transformation of an allylic ether into a homoallylic alcohol via a concerted, pericyclic process. Because the reaction is concerted, it exhibits a high degree of… Wikipedia: Category:Name reactions
Aza-Wittig reaction Olefination The Aza-Wittig reaction or is a chemical reaction of a carbonyl group with an aza-ylide, also known as an iminophosphorane (R3P=NR'). Aza-Wittig reactions are most commonly used to convert aldehydes… Wikipedia: Category:Name reactions
GENERATION OF YNOLATE AND Z-SELECTIVE OLEFINATION OF ACYLSILANES: (Z)-2-METHYL-3-TRIMETHYLSILYL-2-BUTENOIC ACID ((Z)-2-Butenoic acid, 2-methyl-3-trimethylsilyl-) Olefination Preparation of (Z)-2-Butenoic acid, 2-methyl-3-trimethylsilyl-. Submitted by Mitsuru Shindo1, Kenji Matsumoto2, and Kozo Shishido2. DOI: 10.15227/orgsyn.084.0011. Organic Syntheses
Julia olefination Olefination The Julia olefination (also known as the Julia–Lythgoe olefination) is the chemical reaction used in organic chemistry of phenyl sulfones (1) with aldehydes (or ketones) to give alkenes (olefins)(3) a… Wikipedia: Category:Name reactions
Kauffmann olefination Olefination The Kauffmann olefination is a chemical reaction to convert aldehydes and ketones to olefins with a terminal methylene group. This reaction was discovered by the German chemist Thomas Kauffmann and is… Wikipedia: Category:Name reactions
NICKEL-CATALYZED SILYLOLEFINATION OF ALLYLIC DITHIOACETALS: (E,E)-TRIMETHYL(4-PHENYL-1,3-BUTADIENYL)SILANE (Silane, trimethyl (4-phenyl-1,3-butadienyl)-, (E,E)-) Olefination Preparation of Silane, trimethyl (4-phenyl-1,3-butadienyl)-, (E,E)-. Submitted by Zhi-Jie Ni and Tien-Yau Luh1. DOI: 10.15227/orgsyn.070.0240. Organic Syntheses
Peterson olefination Olefination The Peterson olefination (also called the Peterson reaction) is the chemical reaction of α-silyl carbanions (1 in diagram below) with ketones (or aldehydes) to form a β-hydroxysilane (2) which elimina… Wikipedia: Category:Name reactions
PREPARATION OF HORNER-WADSWORTH-EMMONS REAGENT: METHYL 2-BENZYLOXYCARBONYLAMINO-2- (DIMETHOXY- PHOSPHINYL)ACETATE Olefination Preparation of PREPARATION OF HORNER-WADSWORTH-EMMONS REAGENT: METHYL 2-BENZYLOXYCARBONYLAMINO-2- (DIMETHOXY- PHOSPHINYL)ACETATE. Submitted by Hiroki Azuma1, Kentaro Okano1, Tohru Fukuyama2, and Hidet… Organic Syntheses
PREPARATION OF α,β-UNSATURATED ALDEHYDES via THE WITTIG REACTION: CYCLOHEXYLIDENEACETALDEHYDE (Acetaldehyde, cyclohexylidene-) Olefination Preparation of Acetaldehyde, cyclohexylidene-. Submitted by Wataru Nagata1, Toshio Wakabayashi2, and Yoshio Hayase1. DOI: 10.15227/orgsyn.053.0104. Organic Syntheses
SYNTHESIS OF (−)-(E,S)-3-(BENZYLOXY)-1-BUTENYL PHENYL SULFONE VIA A HORNER-WADSWORTH-EMMONS REACTION OF (−)-(S)-2-(BENZYLOXY)PROPANAL (Benzene, [[[1-methyl-3-(phenylsulfonyl)-2-propenyl]oxy]methyl]-, [S-(E)]-) from (Propanal, 2-(phenylmethoxy)-, (S)-)) Olefination Preparation of Benzene, [[[1-methyl-3-(phenylsulfonyl)-2-propenyl]oxy]methyl]-, [S-(E)]-) from (Propanal, 2-(phenylmethoxy)-, (S)-). Submitted by D. Enders1 , S. von Berg1 , and B. Jandeleit2. DOI: 10… Organic Syntheses
Takai olefination Olefination Takai olefination in organic chemistry describes the organic reaction of an aldehyde with a diorganochromium compound to form an alkene. It is a name reaction, named for Kazuhiko Takai, who first repo… Wikipedia: Category:Name reactions
Wittig olefination: methyltriphenylphosphonium bromide + benzaldehyde → styrene Scale Olefination Canonical Wittig olefination — the textbook 'make an alkene from an aldehyde' demo. The ylide (methylenetriphenylphosphorane) is generated in situ from methyltriphenylphosphonium bromide + base (typic… Wittig 1954
WITTIG OLEFINATION OF PERFLUOROALKYL CARBOXYLIC ESTERS; SYNTHESIS OF 1,1,1-TRIFLUORO-2-ETHOXY-5-PHENYLPENT-2-ENE AND 1-PERFLUOROALKYL EPOXY ETHERS: 1,1,1-TRIFLUORO-2-ETHOXY-2,3-EPOXY-5-PHENYLPENTANE ((Benzene, (4-ethoxy-5,5,5-trifluoro-3-pentenyl)-, (Z)- and Oxirane, 2-ethoxy-3-(2-phenylethyl)-2-(trifluoromethyl)-, cis-(±)-)) Olefination Preparation of (Benzene, (4-ethoxy-5,5,5-trifluoro-3-pentenyl)-, (Z)- and Oxirane, 2-ethoxy-3-(2-phenylethyl)-2-(trifluoromethyl)-, cis-(±)-). Submitted by Jean-Pierre Bégué, Danièle Bonnet-Delpon, an… Organic Syntheses
Wittig reaction Olefination The Wittig reaction or Wittig olefination is a chemical reaction of an aldehyde or ketone with a triphenyl phosphonium ylide called a Wittig reagent. Wittig reactions are most commonly used to conve… Wikipedia: Category:Name reactions

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