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44 reactions imported from Wikipedia named-reactions and Organic Syntheses archives. Filter by source or search by name + summary.

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Equation Name Summary Source
[3+2]-ANIONIC ELECTROCYCLIZATION USING 2,3-BIS(PHENYLSULFONYL)-1,3-BUTADIENE: trans-4,7,7-TRICARBOMETHOXY-2-PHENYLSULFONYLBICYCLO[3.3.0]OCT-1-ENE (Benzene, 1,1'-[[1,2-bis(methylene)-1,2-ethanediyl]bis(sulfonyl)]bis-) Cyclization Preparation of Benzene, 1,1'-[[1,2-bis(methylene)-1,2-ethanediyl]bis(sulfonyl)]bis-. Submitted by Albert Padwa1, Scott H. Watterson, and Zhijie Ni. DOI: 10.15227/orgsyn.074.0147. Organic Syntheses
[3 + 4] ANNULATION USING A [β-(TRIMETHYLSILYL)ACRYLOYL]SILANE AND THE LITHIUM ENOLATE OF AN α,β-UNSATURATED METHYL KETONE: (1R,6S,7S)-4-(tert-BUTYLDIMETHYLSILOXY)-6-(TRIMETHYLSILYL)BICYCLO[5.4.0]UNDEC-4-EN-2-ONE Cyclization Preparation of [3 + 4] ANNULATION USING A [β-(TRIMETHYLSILYL)ACRYLOYL]SILANE AND THE LITHIUM ENOLATE OF AN α,β-UNSATURATED METHYL KETONE: (1R,6S,7S)-4-(tert-BUTYLDIMETHYLSILOXY)-6-(TRIMETHYLSILYL)BICY… Organic Syntheses
5-endo-trig CYCLIZATION OF 1,1-DIFLUORO-1-ALKENES: SYNTHESIS OF 3-BUTYL-2-FLUORO-1-TOSYLINDOLE (1H-Indole, 3-butyl-2-fluoro-1-[(4-methylphenyl)sulfonyl]-) Cyclization Preparation of 1H-Indole, 3-butyl-2-fluoro-1-[(4-methylphenyl)sulfonyl]-. Submitted by Junji Ichikawa, Ryo Nadano, Takashi Mori, and Yukinori Wada1. DOI: 10.15227/orgsyn.083.0111. Organic Syntheses
A GENERAL [3+2] ANNULATION: cis-4-exo-ISOPROPENYL-1,9-DIMETHYL-8-(TRIMETHYLSILYL)BICYCLO[4.3.0]NON-8-EN-2-ONE (4H-Inden-4-one, 1,3a,5,6,7,7a-hexahydro-3,3a-dimethyl-6-(1-methylethenyl)-2-(trimethylsilyl)-, (3aα,6α,7aα)-) Cyclization Preparation of 4H-Inden-4-one, 1,3a,5,6,7,7a-hexahydro-3,3a-dimethyl-6-(1-methylethenyl)-2-(trimethylsilyl)-, (3aα,6α,7aα)-. Submitted by Rick L. Danheiser, David M. Fink, and Yeun-Min Tsai1. DOI: 10.… Organic Syntheses
Allan–Robinson reaction Cyclization The Allan–Robinson reaction is the chemical reaction of o-hydroxyaryl ketones with aromatic anhydrides to form flavones (or isoflavones). Wikipedia: Category:Name reactions
Bergman cyclization Cyclization The Masamune-Bergman cyclization or Masamune-Bergman reaction or Masamune-Bergman cycloaromatization is an organic reaction and more specifically a rearrangement reaction taking place when an enediyne… Wikipedia: Category:Name reactions
Borsche–Drechsel cyclization Cyclization The Borsche–Drechsel cyclization is a chemical reaction used to synthesize tetrahydrocarbazoles by the acid-catalyzed cyclization of cyclohexanone arylhydrazones. The reaction was first described by E… Wikipedia: Category:Name reactions
CONJUGATE ADDITION–CYCLIZATION OF A CYANOCUPRATE: 2-CARBOMETHOXY-3-VINYLCYCLOPENTANONE (Cyclopentanecarboxylic acid, 2-ethenyl-5-oxo-, methyl ester) Cyclization Preparation of Cyclopentanecarboxylic acid, 2-ethenyl-5-oxo-, methyl ester. Submitted by William A. Nugent and Frank W. Hobbs, Jr.1. DOI: 10.15227/orgsyn.066.0052. Organic Syntheses
CYCLOBUTANONE via SOLVOLYTIC CYCLIZATION Cyclization Preparation of CYCLOBUTANONE via SOLVOLYTIC CYCLIZATION. Submitted by M. Hanack1, T. Dehesch, K. Hummel, and A. Nierth. DOI: 10.15227/orgsyn.054.0084. Organic Syntheses
CYCLOPENTADIENE ANNULATION VIA THE SKATTEBØL REARRANGEMENT: (1R)-9,9-DIMETHYLTRICYCLO-[6.1.1.02,6]DECA-2,5-DIENE Cyclization Preparation of CYCLOPENTADIENE ANNULATION VIA THE SKATTEBØL REARRANGEMENT: (1R)-9,9-DIMETHYLTRICYCLO-[6.1.1.02,6]DECA-2,5-DIENE. Submitted by Leo A. Paquette and Mark L. McLaughlin1. DOI: 10.15227/org… Organic Syntheses
CYCLOPENTANONE ANNULATION VIA CYCLOPROPANONE DERIVATIVES: (3aβ,9bβ)-1,2,3a,4,5,9b-HEXAHYDRO-9b-HYDROXY-3a-METHYL-3H-BENZ[e]INDEN-3-ONE Cyclization Preparation of CYCLOPENTANONE ANNULATION VIA CYCLOPROPANONE DERIVATIVES: (3aβ,9bβ)-1,2,3a,4,5,9b-HEXAHYDRO-9b-HYDROXY-3a-METHYL-3H-BENZ[e]INDEN-3-ONE. Submitted by Michael J. Bradlee and Paul Helquist… Organic Syntheses
Danheiser annulation Cyclization The Danheiser annulation or Danheiser TMS-cyclopentene annulation is an organic reaction of an α,β-unsaturated ketone and a trialkylsilylallene (e.g., trimethylsilyl- or triisopropylsilyl-) in the pre… Wikipedia: Category:Name reactions
Danheiser benzannulation Cyclization The Danheiser benzannulation is a chemical reaction used in organic chemistry to generate highly substituted phenols in a single step. It is named after Rick L. Danheiser who developed the reaction. Wikipedia: Category:Name reactions
DIAZO KETONE CYCLIZATION ONTO A BENZENE RING: 3,4-DIHYDRO-1(2H)-AZULENONE (1(2H)-Azulenone, 3,4-dihydro-) Cyclization Preparation of 1(2H)-Azulenone, 3,4-dihydro-. Submitted by Lawrence T. Scott and Chris A. Sumpter1. DOI: 10.15227/orgsyn.069.0180. Organic Syntheses
Discussion Addendum for: [3 + 4] Annulation Using a [ß-(Trimethylsilyl) acryloyl]silane and the Lithium Enolate of an a,ß-Unsaturated Methyl Ketone: (1R,6S,7S)-4-(tert-Butyldimethylsiloxy)-6-(trimethylsilyl)bicyclo [5.4.0]undec-4-en-2-one Cyclization Preparation of Discussion Addendum for: [3 + 4] Annulation Using a [ß-(Trimethylsilyl) acryloyl]silane and the Lithium Enolate of an a,ß-Unsaturated Methyl Ketone: (1R,6S,7S)-4-(tert-Butyldimethylsilo… Organic Syntheses
Discussion Addendum for: 5-ENDO-TRIG CYCLIZATION OF 1,1-DIFLUORO-1-ALKENES: SYNTHESIS OF 3-BUTYL-2-FLUORO-1-TOSYLINDOLE (1H-INDOLE, 3-BUTYL-2-FLUORO-1-[(4-METHYLPHENYL)SULFONYL]-) Cyclization Preparation of Discussion Addendum for: 5-ENDO-TRIG CYCLIZATION OF 1,1-DIFLUORO-1-ALKENES: SYNTHESIS OF 3-BUTYL-2-FLUORO-1-TOSYLINDOLE (1H-INDOLE, 3-BUTYL-2-FLUORO-1-[(4-METHYLPHENYL)SULFONYL]-). Subm… Organic Syntheses
Discussion Addendum for: SYNTHESIS OF INDOLES BY PALLADIUM CATALYZED REDUCTIVE N-HETEROANNULATION OF 2-NITROSTYRENES: METHYL INDOLE-4-CARBOXYLATE Cyclization Preparation of Discussion Addendum for: SYNTHESIS OF INDOLES BY PALLADIUM CATALYZED REDUCTIVE N-HETEROANNULATION OF 2-NITROSTYRENES: METHYL INDOLE-4-CARBOXYLATE. Submitted by Björn C. Söderberg.*1. DO… Organic Syntheses
(E)-1-BENZYL-3-(1-IODOETHYLIDENE)PIPERIDINE: NUCLEOPHILE-PROMOTED ALKYNE-IMINIUM ION CYCLIZATIONS (Piperidine, 3-(iodoethylidene)-1-(phenylmethyl)-(E)-) Cyclization Preparation of Piperidine, 3-(iodoethylidene)-1-(phenylmethyl)-(E)-. Submitted by H. Arnold, L. E. Overman, M. J. Sharp, and M. C. Witschel1. DOI: 10.15227/orgsyn.070.0111. Organic Syntheses
ELECTROPHILIC CYCLIZATION WITH N-IODOSUCCINIMIDE: PREPARATION OF 5-(4-BROMOPHENYL)-3-IODO-2-(4-METHYL-PHENYL)FURAN Cyclization Preparation of ELECTROPHILIC CYCLIZATION WITH N-IODOSUCCINIMIDE: PREPARATION OF 5-(4-BROMOPHENYL)-3-IODO-2-(4-METHYL-PHENYL)FURAN. Submitted by Adam Sniady, Marco S. Morreale, and Roman Dembinski1. DO… Organic Syntheses
Ferrier carbocyclization Cyclization The Ferrier carbocyclization (or Ferrier II reaction) is an organic reaction that was first reported by the carbohydrate chemist Robert J. Ferrier in 1979. It is a metal-mediated rearrangement of eno… Wikipedia: Category:Name reactions
FRAGMENTATION-RECOMBINATION NAZAROV CYCLIZATION: 3,4-DIMETHYLCYCLOPENT-2-EN-1-ONE Cyclization Preparation of FRAGMENTATION-RECOMBINATION NAZAROV CYCLIZATION: 3,4-DIMETHYLCYCLOPENT-2-EN-1-ONE. Submitted by Keith D. Schwartz and James D. White1. DOI: 10.15227/orgsyn.083.0049. Organic Syntheses
FREE-RADICAL CYCLIZATION: ETHYL 1-CYANO-2-METHYLCYCLOHEXANECARBOXYLATE (Cyclohexanecarboxylic acid, 1-cyano-2-methyl-, ethyl ester) Cyclization Preparation of Cyclohexanecarboxylic acid, 1-cyano-2-methyl-, ethyl ester. Submitted by Marc Julia and Michel Maumy1. DOI: 10.15227/orgsyn.055.0057. Organic Syntheses
GENERATION AND CYCLIZATION OF 5-HEXENYLLITHIUM: 2-CYCLOPENTYLACETOPHENONE (Ethanone, 2-cyclopentyl-1-phenyl-) Cyclization Preparation of Ethanone, 2-cyclopentyl-1-phenyl-. Submitted by William F. Bailey, Matthew R. Luderer, Michael J. Mealy, and Eric R. Punzalan1. DOI: 10.15227/orgsyn.081.0121. Organic Syntheses
INDOLE SYNTHESIS BY Pd-CATALYZED ANNULATION OF KETONES WITH o-IODOANILINE: 1,2,3,4-TETRAHYDROCARBAZOLE (1H-Carbazole, 2,3,4,9-tetrahydro-) Cyclization Preparation of 1H-Carbazole, 2,3,4,9-tetrahydro-. Submitted by Cheng-yi Chen and Robert D. Larsen1. DOI: 10.15227/orgsyn.078.0036. Organic Syntheses
INTRAMOLECULAR CYCLIZATION OF cis,cis-1,5-CYCLOOCTADIENE USING HYPERVALENT IODINE: BICYCLO[3.3.0]OCTANE-2,6-DIONE (1,4-Pentalenedione, hexahydro-) Cyclization Preparation of 1,4-Pentalenedione, hexahydro-. Submitted by Robert M. Moriarty1, Michael P. Duncan1, Radhe K. Vaid1, and OM Prakash2. DOI: 10.15227/orgsyn.068.0175. Organic Syntheses
IRIDIUM-CATALYZED N-HETEROCYCLIZATION OF PRIMARY AMINES WITH DIOLS: N-BENZYLPIPERIDINE Cyclization Preparation of IRIDIUM-CATALYZED N-HETEROCYCLIZATION OF PRIMARY AMINES WITH DIOLS: N-BENZYLPIPERIDINE. Submitted by Ken-ichi Fujita1a , Youichiro Enoki, and Ryohei Yamaguchi1b. DOI: 10.15227/orgsyn.08… Organic Syntheses
MACROLIDES FROM CYCLIZATION OF ω-BROMOCARBOXYLIC ACIDS: 11-HYDROXYUNDECANOIC LACTONE (Oxacyclododecan-2-one) Cyclization Preparation of Oxacyclododecan-2-one. Submitted by C. Galli and L. Mandolini1. DOI: 10.15227/orgsyn.058.0098. Organic Syntheses
Nazarov cyclization Cyclization The Nazarov cyclization, also known as the Nazarov reaction, is a chemical reaction used in organic chemistry for the synthesis of cyclopentenones. The reaction is typically divided into classical and… Wikipedia: Category:Name reactions
PHOSPHINE-CATALYZED [3 + 2] ANNULATION: SYNTHESIS OF ETHYL 5-(tert-BUTYL)-2-PHENYL-1-TOSYL-3-PYRROLINE-3-CARBOXYLATE Cyclization Preparation of PHOSPHINE-CATALYZED [3 + 2] ANNULATION: SYNTHESIS OF ETHYL 5-(tert-BUTYL)-2-PHENYL-1-TOSYL-3-PYRROLINE-3-CARBOXYLATE. Submitted by Ian P. Andrews and Ohyun Kwon1. DOI: 10.15227/orgsyn.0… Organic Syntheses
PHOSPHINE-CATALYZED [4+2] ANNULATION: SYNTHESIS OF ETHYL 6-PHENYL-1-TOSYL-1,2,5,6-TETRAHYDROPYRIDINE-3-CARBOXYLATE Cyclization Preparation of PHOSPHINE-CATALYZED [4+2] ANNULATION: SYNTHESIS OF ETHYL 6-PHENYL-1-TOSYL-1,2,5,6-TETRAHYDROPYRIDINE-3-CARBOXYLATE. Submitted by Kui Lu and Ohyun Kwon1. DOI: 10.15227/orgsyn.086.0212. Organic Syntheses
PHOTOCYCLIZATION OF AN ENONE TO AN ALKENE: 6-METHYLBICYCLO[4.2.0]OCTAN-2-ONE (Bicyclo[4.2.0]octan-2-one, 6-methyl-) Cyclization Preparation of Bicyclo[4.2.0]octan-2-one, 6-methyl-. Submitted by R. L. Cargill1, J. R. Dalton, G. H. Morton, and W. E. Caldwell1. DOI: 10.15227/orgsyn.062.0118. Organic Syntheses
Preparation of 3-Alkylated Oxindoles from N-Benzyl Aniline via a Cu(II)-Mediated Anilide Cyclization Process Cyclization Preparation of Preparation of 3-Alkylated Oxindoles from N-Benzyl Aniline via a Cu(II)-Mediated Anilide Cyclization Process. Submitted by David S. Pugh1 and Richard J. K. Taylor1. DOI: 10.15227/orgsyn… Organic Syntheses
Preparation of 5-Hydroxycyclopentenones Via Conjugate Addition-Initiated Nazarov Cyclization Cyclization Preparation of Preparation of 5-Hydroxycyclopentenones Via Conjugate Addition-Initiated Nazarov Cyclization. Submitted by Joshua L. Brooks, Yu-Wen Huang, and Alison J. Frontier1*. DOI: 10.15227/orgsyn… Organic Syntheses
Preparation of Tetrahydroisoquinoline-3-ones Via Cyclization of Phenyl Acetamides Using Eaton's Reagent Cyclization Preparation of Preparation of Tetrahydroisoquinoline-3-ones Via Cyclization of Phenyl Acetamides Using Eaton's Reagent. Submitted by Qiang Yang, Luckner G. Ulysse, Mark D. McLaws, Daniel K. Keefe, Pet… Organic Syntheses
Pschorr cyclization Cyclization The Pschorr cyclization is a name reaction in organic chemistry, which was named after its discoverer, the German chemist Robert Pschorr (1868-1930). It describes the intramolecular substitution of ar… Wikipedia: Category:Name reactions
REDUCTIVE ANNULATION OF VINYL SULFONES: BICYCLO[4.3.0.]NON-1-EN-4-ONE (5H-Inden-5-one, 1,2,3,3a,4,6-hexahydro-) Cyclization Preparation of 5H-Inden-5-one, 1,2,3,3a,4,6-hexahydro-. Submitted by Ho-shen Lin and Leo A. Paquette1. DOI: 10.15227/orgsyn.067.0163. Organic Syntheses
Robinson annulation Cyclization The Robinson annulation is a chemical reaction used in organic chemistry for ring formation. It was discovered by Robert Robinson in 1935 as a method to create a six membered ring by forming three new… Wikipedia: Category:Name reactions
Robinson–Gabriel synthesis Cyclization The Robinson–Gabriel synthesis is an organic reaction in which a 2-acylamino-ketone reacts intramolecularly followed by a dehydration to give an oxazole. A cyclodehydrating agent is needed to catalyze… Wikipedia: Category:Name reactions
SYNTHESIS OF 2,3-DISUBSTITUTED INDOLES VIA PALLADIUM-CATALYZED ANNULATION OF INTERNAL ALK YNES: 3-METHYL-2-(TRIMETHYLSILYL)INDOLE Cyclization Preparation of SYNTHESIS OF 2,3-DISUBSTITUTED INDOLES VIA PALLADIUM-CATALYZED ANNULATION OF INTERNAL ALK YNES: 3-METHYL-2-(TRIMETHYLSILYL)INDOLE. Submitted by Yu Chen, Nataliya A. Markina, Tuanli Yao,… Organic Syntheses
SYNTHESIS OF Et2SBr•SbCl5Br AND ITS USE IN BIOMIMETIC BROMINATIVE POLYENE CYCLIZATIONS Cyclization Preparation of SYNTHESIS OF Et2SBr•SbCl5Br AND ITS USE IN BIOMIMETIC BROMINATIVE POLYENE CYCLIZATIONS. Submitted by Scott A. Snyder and Daniel S. Treitler1. DOI: 10.15227/orgsyn.088.0054. Organic Syntheses
SYNTHESIS OF INDOLES BY PALLADIUM-CATALYZED REDUCTIVE N-HETEROANNULATION OF 2-NITROSTYRENES: METHYL INDOLE-4-CARBOXYLATE ((1H-Indole-4-carboxylic acid, methyl ester)) Cyclization Preparation of (1H-Indole-4-carboxylic acid, methyl ester). Submitted by Björn C. Söderberg1, James A. Shriver, and Jeffery M. Wallace. DOI: 10.15227/orgsyn.080.0075. Organic Syntheses
Synthesis of Quinolines by Electrophilic Cyclization of N-(2-Alkynyl)Anilines: 3-Iodo-4-Phenylquinoline Cyclization Preparation of Synthesis of Quinolines by Electrophilic Cyclization of N-(2-Alkynyl)Anilines: 3-Iodo-4-Phenylquinoline. Submitted by Yu Chen, Anton Dubrovskiy, and Richard C. Larock.1,2. DOI: 10.15227… Organic Syntheses
VINYL RADICAL CYCLIZATION VIA ADDITION OF TIN RADICALS TO TRIPLE BONDS: 3-METHYLENE-4-ISOPROPYL-1,1-CYCLOPENTANEDICARBOXYLIC ACID, DIMETHYL ESTER (1,1-Cyclopentanedicarboxylic acid, 3-methylene-4-(1-methylethyl)-, dimethyl ester) Cyclization Preparation of 1,1-Cyclopentanedicarboxylic acid, 3-methylene-4-(1-methylethyl)-, dimethyl ester. Submitted by Robert Mook, Jr. and Philip Michael Sher1. DOI: 10.15227/orgsyn.066.0075. Organic Syntheses
Volhard–Erdmann cyclization Cyclization The Volhard–Erdmann cyclization is an organic synthesis of alkyl and aryl thiophenes by cyclization of disodium succinate or other 1,4-difunctional compounds (γ-oxo acids, 1,4-diketones, chloroacetyl-… Wikipedia: Category:Name reactions

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