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3374 reactions imported from Wikipedia named-reactions and Organic Syntheses archives. Filter by source or search by name + summary.

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Equation Name Summary Source
ASYMMETRIC ALCOHOLYSIS OF MESO-ANHYDRIDES MEDIATED BY ALKALOIDS (Bicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid, 3-endo-benzyloxycarbonyl, (2R,3S)-) Preparation of Bicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid, 3-endo-benzyloxycarbonyl, (2R,3S)-. Submitted by Carsten Bolm1, Iuliana Atodiresei, and Ingo Schiffers. DOI: 10.15227/orgsyn.082.0120. Organic Syntheses
ASYMMETRIC CATALYTIC GLYOXYLATE-ENE REACTION: METHYL (2R)-2-HYDROXY-4-PHENYL-4-PENTENOATE (Benzenebutanoic acid, α-hydroxy-γ-methylene, methyl ester, (R)-) Preparation of Benzenebutanoic acid, α-hydroxy-γ-methylene, methyl ester, (R)-. Submitted by Koichi Mikami, Masahiro Terada, Satoshi Narisawa, and Takeshi Nakai1. DOI: 10.15227/orgsyn.071.0014. Organic Syntheses
ASYMMETRIC EPOXIDATION OF trans-β-METHYLSTYRENE AND 1-PHENYLCYCLOHEXENE USING A D-FRUCTOSE-DERIVED KETONE: (R,R)-trans-β-METHYLSTYRENE OXIDE AND (R,R)-1-PHENYLCYCLOHEXENE OXIDE ((Oxirane, 2-methyl-3-phenyl-, (2R,3R)- and 7-Oxabicyclo[4.1.0]heptane,1-phenyl-)) Oxidation Preparation of (Oxirane, 2-methyl-3-phenyl-, (2R,3R)- and 7-Oxabicyclo[4.1.0]heptane,1-phenyl-). Submitted by Zhi-Xian Wang, Lianhe Shu, Michael Frohn, Yong Tu, and Yian Shi1. DOI: 10.15227/orgsyn.080… Organic Syntheses
ASYMMETRIC HYDROBORATION OF 5-SUBSTITUTED CYCLOPENTADIENES: SYNTHESIS OF METHYL (1 R,5R)-5-HYDROXY-2-CYCLOPENTENE-1-ACETATE (2-Cyclopentene-1-acetic acid, 5-hydroxy-, methyl ester, (1R-trans)-) Addition Preparation of 2-Cyclopentene-1-acetic acid, 5-hydroxy-, methyl ester, (1R-trans)-. Submitted by John J. Partridge, Naresh K. Chadha, and Milan R. Uskokovic1. DOI: 10.15227/orgsyn.063.0044. Organic Syntheses
ASYMMETRIC HYDROGENATION OF 3-OXO CARBOXYLATES USING BINAP-RUTHENIUM COMPLEXES: (R)-(−)-METHYL 3-HYDROXYBUTANOATE (Butanoic acid, 3-hydroxy-, methyl ester, (R)-) Reduction Preparation of Butanoic acid, 3-hydroxy-, methyl ester, (R)-. Submitted by Masato Kitamura, Makoto Tokunaga, Takeshi Ohkuma, and Ryoji Noyori1. DOI: 10.15227/orgsyn.071.0001. Organic Syntheses
ASYMMETRIC HYDROGENATION OF ALLYLIC ALCOHOLS USING BINAP-RUTHENIUM COMPLEXES: (S)-(−)-CITRONELLOL (6-Octen-1-ol, 3,7-dimethyl, (S)-) Reduction Preparation of 6-Octen-1-ol, 3,7-dimethyl, (S)-. Submitted by Hidemasa Takaya1, Tetsuo Ohta1, Shin-ichi Inoue2, Makoto Tokunaga2, Masato Kitamura2, and Ryoji Noyori2. DOI: 10.15227/orgsyn.072.0074. Organic Syntheses
ASYMMETRIC HYDROGENATION OF KETOPANTOYL LACTONE: D-(−)-PANTOYL LACTONE (2(3H)-Furanone, dihydro-3-hydroxy-4,4-dimethyl-) Reduction Preparation of 2(3H)-Furanone, dihydro-3-hydroxy-4,4-dimethyl-. Submitted by I. Ojima, T. Kogure, and Y. Yoda1. DOI: 10.15227/orgsyn.063.0018. Organic Syntheses
ASYMMETRIC REARRANGEMENT OF ALLYLIC TRICHLOROACETIMIDATES: PREPARATION OF (S)-2,2,2-TRICHLORO-N-(1-PROPYLALLYL)ACETAMIDE (Acetamide, 2,2,2-trichloro-N-[(1S)-1-ethenylbutyl]-) Rearrangement Preparation of Acetamide, 2,2,2-trichloro-N-[(1S)-1-ethenylbutyl]-. Submitted by Carolyn E. Anderson, Larry E. Overman*, and Mary P. Watson. DOI: 10.15227/orgsyn.082.0134. Organic Syntheses
ASYMMETRIC REDUCTION OF α,β-ACETYLENIC KETONES WITH B-3-PINANYL-9-BORABICYCLO[3.3.1]NONANE: (R)-( + )-1-OCTYN-3-OL (1-Octyn-3-ol, (R)-) Reduction Preparation of 1-Octyn-3-ol, (R)-. Submitted by M. Mark Midland and Richard S. Graham1. DOI: 10.15227/orgsyn.063.0057. Organic Syntheses
ASYMMETRIC SYNTHESES USING THE SAMP-/RAMP-HYDRAZONE METHOD: (S)-(+)-4-METHYL-3-HEPTANONE (3-Heptanone, 4-methyl, (S)-) Preparation of 3-Heptanone, 4-methyl, (S)-. Submitted by Dieter Enders, Helmut Kipphardt, and Peter Fey1. DOI: 10.15227/orgsyn.065.0183. Organic Syntheses
ASYMMETRIC SYNTHESIS OF 4,4-DIALKYLCYCLOHEXENONES FROM CHIRAL BICYCLIC LACTAMS: (R)-4-ETHYL-4-ALLYL-2-CYCLOHEXEN-1-ONE Preparation of ASYMMETRIC SYNTHESIS OF 4,4-DIALKYLCYCLOHEXENONES FROM CHIRAL BICYCLIC LACTAMS: (R)-4-ETHYL-4-ALLYL-2-CYCLOHEXEN-1-ONE. Submitted by Albert I. Meyers and Daniel Berney1. DOI: 10.15227/o… Organic Syntheses
ASYMMETRIC SYNTHESIS OF DIETHYL (R)-(−)-(1-AMINO-3-METHYLBUTYL)PHOSPHONATE (Phosphonic acid, (1-amino-3-methylbutyl)-, diethyl ester, (R)-) Preparation of Phosphonic acid, (1-amino-3-methylbutyl)-, diethyl ester, (R)-. Submitted by Amos B. Smith, III, Kraig M. Yager, Barton W. Phillips, and Carol M. Taylor1. DOI: 10.15227/orgsyn.075.0019. Organic Syntheses
ASYMMETRIC SYNTHESIS OF (M)-2-HYDROXYMETHYL-1-(2-HYDROXY-4,6-DIMETHYLPHENYL)NAPHTHALENE VIA A CONFIGURATIONALLY UNSTABLE BIARYL LACTONE (2-Naphthalenemethanol, 1-(2-hydroxy-4,6-dimethylphenyl)-, (R)-) Preparation of 2-Naphthalenemethanol, 1-(2-hydroxy-4,6-dimethylphenyl)-, (R)-. Submitted by Gerhard Bringmann1 , Matthias Breuning, Petra Henschel, and Jürgen Hinrichs. DOI: 10.15227/orgsyn.079.0072. Organic Syntheses
ASYMMETRIC SYNTHESIS OF N-tert-BUTOXYCARBONYL α-AMINO ACIDS. SYNTHESIS OF (5S,6R)-4-tert-BUTOXYCARBONYL-5,6-DIPHENYLMORPHOLIN-2-ONE ((4-Morpholinecarboxylic acid, 6-oxo-2,3-diphenyl-, 1,1-dimethylethyl ester, (2S,3R)-)) Preparation of (4-Morpholinecarboxylic acid, 6-oxo-2,3-diphenyl-, 1,1-dimethylethyl ester, (2S,3R)-). Submitted by Robert M. Williams, Peter J. Sinclair, Duane E. DeMong, Daimo Chen, and Dongguan Zhai… Organic Syntheses
ASYMMETRIC SYNTHESIS OF trans-2-AMINOCYCLOHEXANECARBOXYLIC ACID DERIVATIVES FROM PYRROLOBENZODIAZEPINE-5,11-DIONES: (1S,2S)-2-(N-TOSYLAMINO)CYCLOHEXANECARBOXYLIC ACID Preparation of ASYMMETRIC SYNTHESIS OF trans-2-AMINOCYCLOHEXANECARBOXYLIC ACID DERIVATIVES FROM PYRROLOBENZODIAZEPINE-5,11-DIONES: (1S,2S)-2-(N-TOSYLAMINO)CYCLOHEXANECARBOXYLIC ACID. Submitted by Arth… Organic Syntheses
ASYMMETRIC SYNTHESIS OF α-AMINO ACIDS BY THE ALKYLATION OF PSEUDOEPHEDRINE GLYCINAMIDE: L-ALLYLGLYCINE AND N-BOC-L-ALLYLGLYCINE (Acetamide, 2-amino-N-(2-hydroxy-1-methyl-2-phenylethyl)-N-methyl-, [R-(R,R)]-, 4-Pentenoic acid, 2-amino-, (R)- and 4-Pentenoic acid, 2-[[(1,1-dimethylethoxy)carbonyl]amino]-, (R)-)) Preparation of Acetamide, 2-amino-N-(2-hydroxy-1-methyl-2-phenylethyl)-N-methyl-, [R-(R,R)]-, 4-Pentenoic acid, 2-amino-, (R)- and 4-Pentenoic acid, 2-[[(1,1-dimethylethoxy)carbonyl]amino]-, (R)-). Su… Organic Syntheses
Atherton–Todd reaction The Atherton-Todd reaction is a name reaction in organic chemistry, which goes back to the British chemists F. R. Atherton, H. T. Openshaw and A. R. Todd. These described the reaction for the first ti… Wikipedia: Category:Name reactions
ATROLACTIC ACID Preparation of ATROLACTIC ACID. Submitted by Ernest L. Eliel and Jeremiah P. Freeman1. DOI: 10.15227/orgsyn.033.0007. Organic Syntheses
ATROPALDEHYDE (Benzeneacetaldehyde, α-methylene) Preparation of Benzeneacetaldehyde, α-methylene. Submitted by Ingolf Crossland1. DOI: 10.15227/orgsyn.060.0006. Organic Syntheses
AU(I)-CATALYZED HYDRATION OF ALKYNES: 2,8-NONANEDIONE Preparation of AU(I)-CATALYZED HYDRATION OF ALKYNES: 2,8-NONANEDIONE. Submitted by Eiichiro Mizushima,1 Dong-Mei Cui,1 Dilip Chandra Deb Nath,1 Teruyuki Hayashi,*1,2a and Masato Tanaka.1,2b. DOI: 10.1… Organic Syntheses
Auwers synthesis The Auwers synthesis is a series of organic reactions forming a flavonol from a coumarone. This reaction was first reported by Karl von Auwers in 1908. Wikipedia: Category:Name reactions
A WATER-SOLUBLE TIN HYDRIDE: TRIS[3-(2-METHOXYETHOXY)PROPYL]STANNANE (2,5,13,16-Tetraoxa-9-stannaheptadecane, 9-[3-(2-methoxyethoxy)propyl]-) Preparation of 2,5,13,16-Tetraoxa-9-stannaheptadecane, 9-[3-(2-methoxyethoxy)propyl]-. Submitted by James Light and Ronald Breslow1. DOI: 10.15227/orgsyn.072.0199. Organic Syntheses
A XANTHATE-TRANSFER APPROACH TO α-TRIFLUOROMETHYLAMINES (2-(N-ACETYLAMINO)-4,4-DIMETHOXY-1,1,1-TRIFLUOROBUTANE) Preparation of 2-(N-ACETYLAMINO)-4,4-DIMETHOXY-1,1,1-TRIFLUOROBUTANE. Submitted by Fabien Gagosz and Samir Z. Zard1. DOI: 10.15227/orgsyn.084.0032. Organic Syntheses
Aza-Baylis–Hillman reaction The aza-Baylis–Hillman reaction or aza-BH reaction in organic chemistry is a variation of the Baylis–Hillman reaction and describes the reaction of an electron deficient alkene, usually an α,β-unsatur… Wikipedia: Category:Name reactions
Aza-Cope rearrangement Rearrangement Rearrangements, especially those that can participate in cascade reactions, such as the aza-Cope rearrangements, are of high practical as well as conceptual importance in organic chemistry, due to the… Wikipedia: Category:Name reactions
Aza-Diels–Alder reaction The aza-Diels–Alder reaction is a modification of the Diels–Alder reaction wherein a nitrogen replaces sp2 carbon. The nitrogen atom can be part of the diene or the dienophile. Wikipedia: Category:Name reactions
Aza-Wittig reaction Olefination The Aza-Wittig reaction or is a chemical reaction of a carbonyl group with an aza-ylide, also known as an iminophosphorane (R3P=NR'). Aza-Wittig reactions are most commonly used to convert aldehydes… Wikipedia: Category:Name reactions
AZELAIC ACID Preparation of AZELAIC ACID. Submitted by Julian W. Hill and W. L. McEwen. DOI: 10.15227/orgsyn.013.0004. Organic Syntheses
AZELANITRILE Preparation of AZELANITRILE. Submitted by Arthur C. Cope, Robert J. Cotter, and Leland L. Estes1. DOI: 10.15227/orgsyn.034.0004. Organic Syntheses
AZETIDINE Preparation of AZETIDINE. Submitted by Donald H. Wadsworth1. DOI: 10.15227/orgsyn.053.0013. Organic Syntheses
Azide-alkyne Huisgen cycloaddition Cycloaddition The azide-alkyne Huisgen cycloaddition is a 1,3-dipolar cycloaddition between an azide and a terminal or internal alkyne to give a 1,2,3-triazole. Rolf Huisgen was the first to understand the scope of… Wikipedia: Category:Name reactions
AZIRIDINES FROM β-IODOCARBAMATES: 1,2,3,4-TETRAHYDRONAPHTHALENE(1,2)IMINE (1H-Naphth[1,2-b]azirine, 1a,2,3,7b-tetrahydro-) Preparation of 1H-Naphth[1,2-b]azirine, 1a,2,3,7b-tetrahydro-. Submitted by C. H. Heathcock1 and A. Hassner2. DOI: 10.15227/orgsyn.051.0053. Organic Syntheses
AZLACTONE OF α-BENZOYLAMINO-β-(3,4-DIMETHOXYPHENYL)-ACRYLIC ACID (5(4)-Oxazolone, 2-phenyl-4-veratral-) Preparation of 5(4)-Oxazolone, 2-phenyl-4-veratral-. Submitted by Johannes S. Buck and Walter S. Ide. DOI: 10.15227/orgsyn.013.0008. Organic Syntheses
AZOBENZENE Preparation of AZOBENZENE. Submitted by H. E. Bigelow and D. B. Robinson. DOI: 10.15227/orgsyn.022.0028. Organic Syntheses
AZOETHANE (Diazene, diethyl) Preparation of Diazene, diethyl. Submitted by Roland Ohme, Helmut Preuschhof, and Hans-Ulrich Heyne1. DOI: 10.15227/orgsyn.052.0011. Organic Syntheses
AZOXYBENZENE Preparation of AZOXYBENZENE. Submitted by H. E. Bigelow and Albert Palmer. DOI: 10.15227/orgsyn.011.0016. Organic Syntheses
AZULENE Preparation of AZULENE. Submitted by Klaus Hafner and Klaus-Peter Meinhardt1. DOI: 10.15227/orgsyn.062.0134. Organic Syntheses
Babler oxidation Oxidation The Babler oxidation, also known as the Babler–Dauben oxidation, is an organic reaction for the oxidative transposition of tertiary allylic alcohols to enones using pyridinium chlorochromate (PCC): Wikipedia: Category:Name reactions
Baeyer–Drewsen indigo synthesis The Baeyer–Drewsen indigo synthesis (1882) is an organic reaction in which indigo is prepared from 2-nitrobenzaldehyde and acetone The reaction was developed by von Baeyer and Viggo Drewsen in … Wikipedia: Category:Name reactions
Baeyer–Emmerling indole synthesis Baeyer–Emmerling indole synthesis is a method for synthesizing indole from a (substituted) ortho-nitrocinnamic acid and iron powder in strongly basic solution. This reaction was discovered by Adolf vo… Wikipedia: Category:Name reactions
Baeyer–Villiger oxidation Oxidation The Baeyer–Villiger oxidation is an organic reaction that forms an ester from a ketone or a lactone from a cyclic ketone, using peroxyacids or peroxides as the oxidant. The reaction is named after Ado… Wikipedia: Category:Name reactions
Bailey peptide synthesis The Bailey peptide synthesis is a name reaction in organic chemistry developed 1949 by J. L. Bailey. It is a method for the synthesis of a peptide from α-amino acid-N-carboxylic acid anhydrides (NCAs)… Wikipedia: Category:Name reactions
Baker–Venkataraman rearrangement Rearrangement The Baker–Venkataraman rearrangement is the chemical reaction of 2-acetoxyacetophenones with base to form 1,3-diketones. Wikipedia: Category:Name reactions
Balz–Schiemann reaction The Balz–Schiemann reaction (also called the Schiemann reaction) is a chemical reaction in which an aryl diazonium salt is transformed to an aryl fluoride. This reaction is a traditional route to fluo… Wikipedia: Category:Name reactions
Bamberger rearrangement Rearrangement The Bamberger rearrangement is the chemical reaction of phenylhydroxylamines with strong aqueous acid, which will rearrange to give 4-aminophenols. It is named for the German chemist Eugen Bamberger (… Wikipedia: Category:Name reactions
Bamberger triazine synthesis The Bamberger triazine synthesis in organic chemistry is a classic organic synthesis of a triazine first reported by Eugen Bamberger in 1892. Wikipedia: Category:Name reactions
Bamford–Stevens reaction The Bamford–Stevens reaction is a chemical reaction whereby treatment of tosylhydrazones with strong base gives alkenes. It is named for the British chemist William Randall Bamford and the Scottish ch… Wikipedia: Category:Name reactions
Banert cascade The Banert cascade is an organic reaction in which an NH-1,2,3-triazole is prepared from a propargyl halide or sulfate and sodium azide in a dioxane- water mixture at elevated temperatures. It is name… Wikipedia: Category:Name reactions
Barbier reaction Organometallic addition The Barbier reaction is an organometallic reaction between an alkyl halide (chloride, bromide, iodide), a carbonyl group and a metal. The reaction can be performed using magnesium, aluminium, zinc, in… Wikipedia: Category:Name reactions
Barbier–Wieland degradation Organometallic addition The Barbier–Wieland degradation is a procedure for shortening the carbon chain of a carboxylic acid by one carbon. It only works when the carbon adjacent to the carboxyl is a simple methylene bridge (… Wikipedia: Category:Name reactions

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