SYNTHESIS OF (−)-(E,S)-3-(BENZYLOXY)-1-BUTENYL PHENYL SULFONE VIA A HORNER-WADSWORTH-EMMONS REACTION OF (−)-(S)-2-(BENZYLOXY)PROPANAL (Benzene, [[[1-methyl-3-(phenylsulfonyl)-2-propenyl]oxy]methyl]-, [S-(E)]-) from (Propanal, 2-(phenylmethoxy)-, (S)-))
Organic SynthesesOlefination
A checked procedure from Organic Syntheses, the journal whose preparations are repeated in a second laboratory before publication. The full experimental, with amounts, hazards and characterisation data, is on orgsyn.org.
Reagents
The compound this preparation makes is not in the catalogue, so no reagents or figures are listed here.
Named reactions in this procedure
More olefination reactions
- Generation of ynolate and Z-selective olefination of acylsilanes: (Z)-2-methyl-3-trimethylsilyl-2-butenoic acid
- Nickel-catalyzed silylolefination of allylic dithioacetals: (E,E)-trimethyl(4-phenyl-1,3-butadienyl)silane
- Preparation of Horner-Wadsworth-Emmons reagent: methyl 2-benzyloxycarbonylamino-2- (dimethoxy- phosphinyl)acetate
- Preparation of α,β-unsaturated aldehydes via the Wittig reaction: cyclohexylideneacetaldehyde
- Wittig olefination of perfluoroalkyl carboxylic esters; synthesis of 1,1,1-trifluoro-2-ethoxy-5-phenylpent-2-ene and 1-perfluoroalkyl epoxy ethers: 1,1,1-trifluoro-2-ethoxy-2,3-epoxy-5-phenylpentane
- Aza-Wittig reaction