Generation of ynolate and Z-selective olefination of acylsilanes: (Z)-2-methyl-3-trimethylsilyl-2-butenoic acid
CAS index name: (Z)-2-Butenoic acid, 2-methyl-3-trimethylsilyl-
Organic SynthesesOlefination
A checked procedure from Organic Syntheses, the journal whose preparations are repeated in a second laboratory before publication. The full experimental, with amounts, hazards and characterisation data, is on orgsyn.org.
Reagents
The compound this preparation makes is not in the catalogue, so no reagents or figures are listed here.
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- Preparation of α,β-unsaturated aldehydes via the Wittig reaction: cyclohexylideneacetaldehyde
- SYNTHESIS OF (−)-(E,S)-3-(BENZYLOXY)-1-BUTENYL PHENYL SULFONE VIA A HORNER-WADSWORTH-EMMONS REACTION OF (−)-(S)-2-(BENZYLOXY)PROPANAL (Benzene, [[[1-methyl-3-(phenylsulfonyl)-2-propenyl]oxy]methyl]-, [S-(E)]-) from (Propanal, 2-(phenylmethoxy)-, (S)-))
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