Acyloin condensation in which chlorotrimethylsilane is used as a trapping agent: 1,2-bis(trimethylsilyloxy)cyclobutene and 2-hydroxycyclobutanone
CAS index name: Trimethylsilane, 1-cyclobuten-1,2-ylenedioxybis- and Cyclobutanone, 2-hydroxy-
Organic SynthesesCondensation
A checked procedure from Organic Syntheses, the journal whose preparations are repeated in a second laboratory before publication. The full experimental, with amounts, hazards and characterisation data, is on orgsyn.org.
Reagents
The compound this preparation makes is not in the catalogue, so no reagents or figures are listed here.
More condensation reactions
- Acyloin condensation by thiazolium ion catalysis: butyroin
- Amide formation by decarboxylative condensation of hydroxylamines and α-ketoacids: N-[(1S)-1 phenylethyl]-benzeneacetamide
- Catalytic asymmetric acyl halide-aldehyde cyclocondensation reaction
- Catalytic asymmetric synthesis of nitroaldols using a lanthanum-lithium-BINOL complex: (2S,3S)-2-nitro-5-phenyl-1,3-pentanediol
- Condensation of (−)-dimenthyl succinate dianion with 1,ω-dihalides: (+)-(1S,2S)-cyclopropane-1,2-dicarboxylic acid
- Condensation of dimethyl 1,3-acetonedicarboxylate with 1,2-dicarbonyl compounds: cis-bicyclo[3.3.0]octane-3,7-diones