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  1. Darzens halogenationHalogenation Darzens halogenation is the chemical synthesis of alkyl halides from alcohols via the treatment upon reflux of a large excess of thionyl chloride or thionyl bromide (SOX2) in the presence of a small amount of a nitrogen base, such as a tertiary amine or pyridine or its corresponding hydrochloride or hydrobromide salt. Named reaction · Wikipedia
  2. Hell–Volhard–Zelinsky halogenationHalogenation The Hell–Volhard–Zelinsky halogenation reaction is a chemical transformation that transforms an alkyl carboxylic acid to the α-bromo derivative. Named reaction · Wikipedia
  3. Alkyne via solid-liquid phase-transfer catalyzed dehydrohalogenation: acetylene dicarboxaldehyde tetramethyl acetal and acetylene dicarboxaldehyde dimethyl acetalHalogenation Org. Synth. Vol. 82, p. 179 · Akué-Gédu and Rigo
  4. Alkynes via phase transfer–catalyzed dehydrohalogenation: propiolaldehyde diethyl acetalHalogenation Org. Synth. Coll. Vol. 6, p. 954; Vol. 59, p. 10 · Coq and Gorgues