chempirical
Reaction database

Rearrangement reactions

3,374 reactions: 10 worked examples with a reagent table you can scale, 503 named reactions and 2,861 checked procedures from Organic Syntheses.

1–24 of 31

  1. 1-N-Acylamino-1,3-dienes from 2,4-pentadienoic acids by the Curtius rearrangement: benzyl trans-1,3-butadiene-1-carbamateRearrangement Org. Synth. Coll. Vol. 6, p. 95; Vol. 59, p. 1 · Jessup et al.
  2. Alkenes via Hofmann elimination: use of ion-exchange resin for preparation of quaternary ammonium hydroxides: diphenylmethyl vinyl etherRearrangement Org. Synth. Coll. Vol. 6, p. 552; Vol. 55, p. 3 · Kaiser and Weinstock
  3. Allyl Cyanate-To-Isocyanate Rearrangement: Preparation of tert-Butyl 3,7-dimethylocta-1,6-dien-3-ylcarbamateRearrangement Org. Synth. Vol. 90, p. 271 · Ichikawa et al.
  4. Asymmetric rearrangement of allylic trichloroacetimidates: preparation of (S)-2,2,2-trichloro-N-(1-propylallyl)acetamideRearrangement Org. Synth. Vol. 82, p. 134 · Anderson et al.
  5. Base-induced rearrangement of epoxides to allylic alcohols: trans-pinocarveol (Bicyclo[3.3.1]heptan-3-ol, 6,6-dimethyl-2-methylene-, (1α,3α,5α-)Rearrangement Org. Synth. Coll. Vol. 6, p. 948; Vol. 53, p. 17 · Crandall and Crawley
  6. BenzalpinacoloneRearrangement Org. Synth. Coll. Vol. 1, p. 81; Vol. 5, p. 15 · Hill and Bramann
  7. BenzopinacolRearrangement Org. Synth. Coll. Vol. 2, p. 71; Vol. 14, p. 8 · Bachmann
  8. β-BenzopinacoloneRearrangement Org. Synth. Coll. Vol. 2, p. 73; Vol. 14, p. 12 · Bachmann
  9. Bis(pinacolato)diboronRearrangement Org. Synth. Vol. 77, p. 176 · Ishiyama et al.
  10. Direct nucleophilic acylation by the low-temperature, in situ generation of acyllithium reagents; α-hydroxy ketones from ketones: 3-hydroxy-2,2,3-trimethyloctan-4-one from pinacoloneRearrangement Org. Synth. Coll. Vol. 8, p. 343; Vol. 69, p. 114 · Hui and Seyferth
  11. Discussion Addendum for: dl-Selective Pinacol-Type Coupling Using Zinc, Chlorosilane, and Catalytic Amounts of Cp2VCl2; dl-1,2-DicyclohexylethanediolRearrangement Org. Synth. Vol. 89, p. 73 · Amaya and Hirao*
  12. dl-selective pinacol-type coupling using zinc, chlorosilane, and catalytic amounts of Cp2VCl2; dl-1,2-dicyclohexylethanediolRearrangement Org. Synth. Vol. 81, p. 26 · Hirao et al.
  13. Formation and photochemical Wolff rearrangement of cyclic α-diazo ketones: D-norandrost-5-en-3β-ol-16-carboxylic acidsRearrangement Org. Synth. Coll. Vol. 6, p. 840; Vol. 52, p. 53 · Wheeler and Meinwald
  14. Hofmann rearrangement under mildly acidic conditions using [I,I-bis(trifluoroacetoxy)]iodobenzene: cyclobutylamine hydrochloride from cyclobutanecarboxamideRearrangement Org. Synth. Coll. Vol. 8, p. 132; Vol. 66, p. 132 · Almond et al.
  15. Intermolecular retro-Cope Type Hydroxylamination of Alkynes with NH2OH: E-1-(1-Hydroxycyclohexyl)ethanone oximeRearrangement Org. Synth. Vol. 90, p. 87 · Loiseau and Beauchemin
  16. 1,2-Metallate rearrangement: (Z)-4-(2-propenyl)-3-octen-1-olRearrangement Org. Synth. Vol. 79, p. 11 · Jarowicki et al.
  17. Methyl carbamate formation via modified Hofmann rearrangement reactions: methyl N-(p-methoxyphenyl)carbamateRearrangement Org. Synth. Vol. 78, p. 234 · Keillor and Huang
  18. Mild and efficient one-pot Curtius rearrangement: preparation of N-tert-butyl adamantanyl-1-yl-carbamateRearrangement Org. Synth. Vol. 86, p. 113 · Leogane and Lebel
  19. Phase-transfer Hofmann carbylamine reaction: tert-butyl isocyanideRearrangement Org. Synth. Coll. Vol. 6, p. 232; Vol. 55, p. 96 · Gokel et al.
  20. Pinacol hydrateRearrangement Org. Synth. Coll. Vol. 1, p. 459; Vol. 5, p. 87 · Adams and Adams
  21. PinacoloneRearrangement Org. Synth. Coll. Vol. 1, p. 462; Vol. 5, p. 91 · Hill and Flosdorf
  22. Rearrangement of 4-aryl-4-hydroxy-2,3-dialkoxycyclobutenones to annulated hydroquinones and quinones: 5,6-diethoxybenzofuran-4,7-dioneRearrangement Org. Synth. Coll. Vol. 8, p. 179; Vol. 69, p. 220 · Perri et al.
  23. Rearrangement of bridgehead alcohols to polycyclic ketones by fragmentation-cyclization: 4-protoadamantanone (tricyclo-[4.3.1.03,8]decan-4-one)Rearrangement Org. Synth. Coll. Vol. 6, p. 958; Vol. 59, p. 147 · Majerski and Hamersak
  24. Rearrangement of trans-stilbene oxide to diphenylacetaldehyde with catalytic methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide)Rearrangement Org. Synth. Coll. Vol. 9, p. 356; Vol. 72, p. 95 · Ooi et al.