chempirical
Reaction database

Rearrangement reactions

3,374 reactions: 10 worked examples with a reagent table you can scale, 503 named reactions and 2,861 checked procedures from Organic Syntheses.

73–95 of 95

  1. Bis(pinacolato)diboronRearrangement Org. Synth. Vol. 77, p. 176 · Ishiyama et al.
  2. Direct nucleophilic acylation by the low-temperature, in situ generation of acyllithium reagents; α-hydroxy ketones from ketones: 3-hydroxy-2,2,3-trimethyloctan-4-one from pinacoloneRearrangement Org. Synth. Coll. Vol. 8, p. 343; Vol. 69, p. 114 · Hui and Seyferth
  3. Discussion Addendum for: dl-Selective Pinacol-Type Coupling Using Zinc, Chlorosilane, and Catalytic Amounts of Cp2VCl2; dl-1,2-DicyclohexylethanediolRearrangement Org. Synth. Vol. 89, p. 73 · Amaya and Hirao*
  4. dl-selective pinacol-type coupling using zinc, chlorosilane, and catalytic amounts of Cp2VCl2; dl-1,2-dicyclohexylethanediolRearrangement Org. Synth. Vol. 81, p. 26 · Hirao et al.
  5. Formation and photochemical Wolff rearrangement of cyclic α-diazo ketones: D-norandrost-5-en-3β-ol-16-carboxylic acidsRearrangement Org. Synth. Coll. Vol. 6, p. 840; Vol. 52, p. 53 · Wheeler and Meinwald
  6. Hofmann rearrangement under mildly acidic conditions using [I,I-bis(trifluoroacetoxy)]iodobenzene: cyclobutylamine hydrochloride from cyclobutanecarboxamideRearrangement Org. Synth. Coll. Vol. 8, p. 132; Vol. 66, p. 132 · Almond et al.
  7. Intermolecular retro-Cope Type Hydroxylamination of Alkynes with NH2OH: E-1-(1-Hydroxycyclohexyl)ethanone oximeRearrangement Org. Synth. Vol. 90, p. 87 · Loiseau and Beauchemin
  8. 1,2-Metallate rearrangement: (Z)-4-(2-propenyl)-3-octen-1-olRearrangement Org. Synth. Vol. 79, p. 11 · Jarowicki et al.
  9. Methyl carbamate formation via modified Hofmann rearrangement reactions: methyl N-(p-methoxyphenyl)carbamateRearrangement Org. Synth. Vol. 78, p. 234 · Keillor and Huang
  10. Mild and efficient one-pot Curtius rearrangement: preparation of N-tert-butyl adamantanyl-1-yl-carbamateRearrangement Org. Synth. Vol. 86, p. 113 · Leogane and Lebel
  11. Phase-transfer Hofmann carbylamine reaction: tert-butyl isocyanideRearrangement Org. Synth. Coll. Vol. 6, p. 232; Vol. 55, p. 96 · Gokel et al.
  12. Pinacol hydrateRearrangement Org. Synth. Coll. Vol. 1, p. 459; Vol. 5, p. 87 · Adams and Adams
  13. PinacoloneRearrangement Org. Synth. Coll. Vol. 1, p. 462; Vol. 5, p. 91 · Hill and Flosdorf
  14. Rearrangement of 4-aryl-4-hydroxy-2,3-dialkoxycyclobutenones to annulated hydroquinones and quinones: 5,6-diethoxybenzofuran-4,7-dioneRearrangement Org. Synth. Coll. Vol. 8, p. 179; Vol. 69, p. 220 · Perri et al.
  15. Rearrangement of bridgehead alcohols to polycyclic ketones by fragmentation-cyclization: 4-protoadamantanone (tricyclo-[4.3.1.03,8]decan-4-one)Rearrangement Org. Synth. Coll. Vol. 6, p. 958; Vol. 59, p. 147 · Majerski and Hamersak
  16. Rearrangement of trans-stilbene oxide to diphenylacetaldehyde with catalytic methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide)Rearrangement Org. Synth. Coll. Vol. 9, p. 356; Vol. 72, p. 95 · Ooi et al.
  17. Ring contraction via a Favorskii-type rearrangement: cycloundecanoneRearrangement Org. Synth. Coll. Vol. 6, p. 368; Vol. 56, p. 107 · Wohllebe and Jr
  18. Silver-catalyzed rearrangement of propargylic sulfinates: synthesis of allenic sulfonesRearrangement Org. Synth. Vol. 88, p. 309 · Harmata et al.
  19. Stereocontrolled preparation of 3-acyltetrahydrofurans from acid-promoted rearrangements of allylic ketals: (2S,3S)-3-acetyl-8-carboethoxy-2,3-dimethyl-1-oxa-8-azaspiro[4.5]decaneRearrangement Org. Synth. Coll. Vol. 9, p. 4; Vol. 71, p. 63 · Overman and Rishton
  20. Synthesis of an N-substituted lactam using an intramolecular Schmidt reaction: formation of 2,3,11,11a-tetrahydro-1H-benzo[d]pyrrolo[1,2-a]azepin-5(6H)-oneRearrangement Org. Synth. Vol. 84, p. 347 · Grecian and Aubé
  21. Synthesis of Arylboronic Pinacol Esters from Corresponding ArylaminesRearrangement Org. Synth. Vol. 91, p. 106 · Qiu et al.
  22. The Carroll rearrangement: 5-dodecen-2-oneRearrangement Org. Synth. Coll. Vol. 8, p. 235; Vol. 68, p. 210 · Wilson and Augelli
  23. α-Unsubstituted γ,δ-unsaturated aldehydes by Claisen rearrangement: 3-phenyl-4-pentenalRearrangement Org. Synth. Coll. Vol. 8, p. 536; Vol. 66, p. 29 · Vogel and Büchi