Chempirical
Reactions
NICKEL-CATALYZED ASYMMETRIC NEGISHI CROSS-COUPLINGS OF RACEMIC SECONDARY ALLYLIC CHLORIDES WITH ALKYLZINCS: (S,E)-ETHYL 6-(1,3-DIOXOLAN-2-YL)-4-METHYLHEX-2-ENOATE (2-Hexenoic acid, 6-(1,3-dioxolan-2-yl)-4-methyl-, ethyl ester, (2E,4S)-)

Reactions · Organic Syntheses

NICKEL-CATALYZED ASYMMETRIC NEGISHI CROSS-COUPLINGS OF RACEMIC SECONDARY ALLYLIC CHLORIDES WITH ALKYLZINCS: (S,E)-ETHYL 6-(1,3-DIOXOLAN-2-YL)-4-METHYLHEX-2-ENOATE (2-Hexenoic acid, 6-(1,3-dioxolan-2-yl)-4-methyl-, ethyl ester, (2E,4S)-)

Reaction equation for NICKEL-CATALYZED ASYMMETRIC NEGISHI CROSS-COUPLINGS OF RACEMIC SECONDARY ALLYLIC CHLORIDES WITH ALKYLZINCS: (S,E)-ETHYL 6-(1,3-DIOXOLAN-2-YL)-4-METHYLHEX-2-ENOATE (2-Hexenoic acid, 6-(1,3-dioxolan-2-yl)-4-methyl-, ethyl ester, (2E,4S)-)

Preparation of 2-Hexenoic acid, 6-(1,3-dioxolan-2-yl)-4-methyl-, ethyl ester, (2E,4S)-. Submitted by Sha Lou and Gregory C. Fu1. DOI: 10.15227/orgsyn.087.0317.

This entry doesn't have stoichiometric equivalents on file yet — the Reaction Scale Calculator needs at least one participant tagged with an equivalents value.
Mechanism / source ↗

Overview

Actions