Chempirical
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IRIDIUM-CATALYZED C-H BORYLATION OF ARENES AND HETEROARENES: 1-CHLORO-3-IODO-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE AND 2-(4,4,5,5,-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)INDOLE ((2-(3-Chloro-5-iodophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane) (2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole))

Reactions · Organic Syntheses

IRIDIUM-CATALYZED C-H BORYLATION OF ARENES AND HETEROARENES: 1-CHLORO-3-IODO-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE AND 2-(4,4,5,5,-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)INDOLE ((2-(3-Chloro-5-iodophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane) (2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole))

Reaction equation for IRIDIUM-CATALYZED C-H BORYLATION OF ARENES AND HETEROARENES: 1-CHLORO-3-IODO-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE AND 2-(4,4,5,5,-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)INDOLE ((2-(3-Chloro-5-iodophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane) (2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole))

Preparation of (2-(3-Chloro-5-iodophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane) (2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole). Submitted by Tatsuo Ishiyama, Jun Takagi, Yusuke Nobuta, and Norio Miyaura1. DOI: 10.15227/orgsyn.082.0126.

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