Reactions · Organic Syntheses

PHOTOINDUCED-ADDITION OF METHANOL TO (5S)-(5-O-tert-BUTYLDIMETHYLSILOXYMETHYL)FURAN-2(5H)-ONE: (4R,5S)-4-HYDROXYMETHYL-(5-O-tert-BUTYLDIMETHYLSILOXYMETHYL)FURAN-2(5H)-ONE (2(5H)-Furanone, 5-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-, (S)- and D-erythro-Pentonic acid, 2,3-dideoxy-5-O-[(1,1-dimethylethyl)dimethylsilyl]-3-(hydroxymethyl)-, γ-lactone)

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Reaction equation for PHOTOINDUCED-ADDITION OF METHANOL TO (5S)-(5-O-tert-BUTYLDIMETHYLSILOXYMETHYL)FURAN-2(5H)-ONE: (4R,5S)-4-HYDROXYMETHYL-(5-O-tert-BUTYLDIMETHYLSILOXYMETHYL)FURAN-2(5H)-ONE (2(5H)-Furanone, 5-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-, (S)- and D-erythro-Pentonic acid, 2,3-dideoxy-5-O-[(1,1-dimethylethyl)dimethylsilyl]-3-(hydroxymethyl)-, γ-lactone)

Preparation of 2(5H)-Furanone, 5-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-, (S)- and D-erythro-Pentonic acid, 2,3-dideoxy-5-O-[(1,1-dimethylethyl)dimethylsilyl]-3-(hydroxymethyl)-, γ-lactone. Submitted by John Mann and Alexander C. Weymouth-Wilson1. DOI: 10.15227/orgsyn.075.0139.

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