Cyclopentadiene annulation via the Skattebøl rearrangement: (1R)-9,9-dimethyltricyclo-[6.1.1.02,6]deca-2,5-diene
Organic SynthesesCyclization
![Reaction scheme of Cyclopentadiene annulation via the Skattebøl rearrangement: (1R)-9,9-dimethyltricyclo-[6.1.1.02,6]deca-2,5-diene from Organic Syntheses](/orgsyn-image/CV8P0223.gif)
A checked procedure from Organic Syntheses, the journal whose preparations are repeated in a second laboratory before publication. The full experimental, with amounts, hazards and characterisation data, is on orgsyn.org.
Reagents
The compound this preparation makes is not in the catalogue, so no reagents or figures are listed here.
Named reactions in this procedure
More cyclization reactions
- [3+2]-Anionic electrocyclization using 2,3-bis(phenylsulfonyl)-1,3-butadiene: trans-4,7,7-tricarbomethoxy-2-phenylsulfonylbicyclo[3.3.0]oct-1-ene
- [3 + 4] Annulation using a [β-(trimethylsilyl)acryloyl]silane and the lithium enolate of an α,β-unsaturated methyl ketone: (1R,6S,7S)-4-(tert-butyldimethylsiloxy)-6-(trimethylsilyl)bicyclo[5.4.0]undec-4-en-2-one
- (E)-1-Benzyl-3-(1-iodoethylidene)piperidine: nucleophile-promoted alkyne-iminium ion cyclizations
- Conjugate addition–cyclization of a cyanocuprate: 2-carbomethoxy-3-vinylcyclopentanone
- Cyclobutanone via solvolytic cyclization
- Cyclopentanone annulation via cyclopropanone derivatives: (3aβ,9bβ)-1,2,3a,4,5,9b-hexahydro-9b-hydroxy-3a-methyl-3H-benz[e]inden-3-one