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2861 reactions imported from Wikipedia named-reactions and Organic Syntheses archives. Filter by source or search by name + summary.

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Equation Name Summary Source
RHODIUM-CATALYZED HETEROCYCLOADDITION OF A DIAZOMALONATE AND A NITRILE: 4-CARBOMETHOXY-5-METHOXY-2-PHENYL-1,3-OXAZOLE (4-Oxazolecarboxylic acid, 5-methoxy-2-phenyl-, methyl ester) Cycloaddition Preparation of 4-Oxazolecarboxylic acid, 5-methoxy-2-phenyl-, methyl ester. Submitted by Joshua S. Tullis and Paul Helquist1. DOI: 10.15227/orgsyn.074.0229. Organic Syntheses
RICINELAIDIC ACID LACTONE (9-Octadecenoic acid, 12-hydroxy-, [(+)-(R)-trans]-, lactone) Preparation of 9-Octadecenoic acid, 12-hydroxy-, [(+)-(R)-trans]-, lactone. Submitted by Adolf Thalmann, Konrad Oertle, and Hans Gerlach1. DOI: 10.15227/orgsyn.063.0192. Organic Syntheses
RING-CLOSING METATHESIS SYNTHESIS OF N-Boc-3-PYRROLINE ((1H-Pyrrole-1-carboxylic acid, 2,5-dihydro-, 1,1-dimethylethyl ester)) Metathesis Preparation of (1H-Pyrrole-1-carboxylic acid, 2,5-dihydro-, 1,1-dimethylethyl ester). Submitted by Marcelle L. Ferguson1, Daniel J. O'Leary1, and Robert H. Grubbs2. DOI: 10.15227/orgsyn.080.0085. Organic Syntheses
RING CONTRACTION via A FAVORSKII-TYPE REARRANGEMENT: CYCLOUNDECANONE Rearrangement Preparation of RING CONTRACTION via A FAVORSKII-TYPE REARRANGEMENT: CYCLOUNDECANONE. Submitted by J. Wohllebe and E. W. Garbisch Jr1. DOI: 10.15227/orgsyn.056.0107. Organic Syntheses
RING EXPANSION AND CLEAVAGE OF SUCCINOIN DERIVATIVES: SPIRO[4.5]DECANE-1,4-DIONE AND ETHYL 4-CYCLOHEXYL-4-OXOBUTANOATE (Cyclohexanebutanoic acid, γ-oxo-, ethyl ester) Preparation of Cyclohexanebutanoic acid, γ-oxo-, ethyl ester. Submitted by Eiichi Nakamura and Isao Kuwajima1. DOI: 10.15227/orgsyn.065.0017. Organic Syntheses
(R)-(−)-N,N-DIETHYL-(E)-CITRONELLALENAMINE AND (R)-(+)-CITRONELLAL VIA ISOMERIZATION OF N,N-DIETHYLGERANYLAMINE OR N,N-DIETHYLNERYLAMINE (1-(E), 6-Octadienamine, (R)-(−)-N,N-diethyl-3,7-dimethyl- and 6-octenal, 3,7-dimethyl-, (R)-(+)-) Preparation of 1-(E), 6-Octadienamine, (R)-(−)-N,N-diethyl-3,7-dimethyl- and 6-octenal, 3,7-dimethyl-, (R)-(+)-. Submitted by Kazuhide Tani1, Tsuneaki Yamagata1, Sei Otsuka1, Hidenori Kumobayashi2, an… Organic Syntheses
(R,R)-1,2-DIPHENYL-1,2-ETHANEDIOL (STILBENE DIOL) (1,2-Ethanediol, 1,2-diphenyl-[R-(R,R)]-) Preparation of 1,2-Ethanediol, 1,2-diphenyl-[R-(R,R)]-. Submitted by Blaine H. McKee1, Declan G. Gilheany2, and K. Barry Sharpless1. DOI: 10.15227/orgsyn.070.0047. Organic Syntheses
(R,R)-2,2'-BISPYRROLIDINE AND (S,S)-2,2'-BISPYRROLIDINE: USEFUL LIGANDS FOR ASYMMETRIC SYNTHESIS Preparation of (R,R)-2,2'-BISPYRROLIDINE AND (S,S)-2,2'-BISPYRROLIDINE: USEFUL LIGANDS FOR ASYMMETRIC SYNTHESIS. Submitted by Scott E. Denmark, Jiping Fu, and Michael J. Lawler1. DOI: 10.15227/orgsyn.… Organic Syntheses
(R,R)- AND (S,S)-N,N'-DIMETHYL-1,2-DIPHENYLETHYLENE-1,2-DIAMINE (1,2-Ethanediamine, N,N'-dimethyl-1,2-diphenyl-, [R-(R,R)]- and [S-(R,R)-]) Preparation of 1,2-Ethanediamine, N,N'-dimethyl-1,2-diphenyl-, [R-(R,R)]- and [S-(R,R)-]. Submitted by Alex Alexakis, Isabelle Aujard, Tonis Kanger, and Pierre Mangeney1. DOI: 10.15227/orgsyn.076.0023… Organic Syntheses
(R,R)-N,N'-BIS(3,5-DI-tert-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO MANGANESE(III) CHLORIDE, A HIGHLY ENANTIOSELECTIVE EPOXIDATION CATALYST (Manganese, chloro[[2,2'-[1,2-cyclohexanediylbis(nitrilomethylidyne)]-bis[4,6-bis(1,1-dimethylethyl)phenalato]](2-)-N,N',O,O']-, [SP-5-13-(1R-trans-]-) Oxidation Preparation of Manganese, chloro[[2,2'-[1,2-cyclohexanediylbis(nitrilomethylidyne)]-bis[4,6-bis(1,1-dimethylethyl)phenalato]](2-)-N,N',O,O']-, [SP-5-13-(1R-trans-]-. Submitted by Jay F. Larrow and Eri… Organic Syntheses
(RS)-(+)-2-METHYL-2-PROPANESULFINAMIDE (tert-Butanesulfinamide) Preparation of tert-Butanesulfinamide. Submitted by Daniel J. Weix and Jonathan A. Ellman1. DOI: 10.15227/orgsyn.082.0157. Organic Syntheses
(R,S)-MEVALONOLACTONE-2-13C (2H-Pyran-2-one-13C, tetrahydro-4-hydroxy-4-methyl-) Preparation of 2H-Pyran-2-one-13C, tetrahydro-4-hydroxy-4-methyl-. Submitted by Masato Tanabe and Richard H. Peters1. DOI: 10.15227/orgsyn.060.0092. Organic Syntheses
RUTHENIUM-CATALYZED ALKYLATION OF AROMATIC KETONES WITH OLEFINS: 8-[2-(TRIETHOXYSILYL)ETHYL]-1-TETRALONE ((1(2H)-Naphthalenone, 3,4-dihydro-8-[2-(triethoxysilyl)ethyl]-)) Preparation of (1(2H)-Naphthalenone, 3,4-dihydro-8-[2-(triethoxysilyl)ethyl]-). Submitted by Fumitoshi Kakiuchi and Shinji Murai1. DOI: 10.15227/orgsyn.080.0104. Organic Syntheses
RUTHENIUM-CATALYZED ARYLATION OF ORTHO C-H BOND IN AN AROMATIC WITH AN ARYLBORONATE: 8-PHENYL-1-TETRALONE Preparation of RUTHENIUM-CATALYZED ARYLATION OF ORTHO C-H BOND IN AN AROMATIC WITH AN ARYLBORONATE: 8-PHENYL-1-TETRALONE. Submitted by Kentaroh Kitazawa, Takuya Kochi, and Fumitoshi Kakiuchi1. DOI: 10… Organic Syntheses
RUTHENOCENE (Ruthenium, dicyclopentadienyl-) Preparation of Ruthenium, dicyclopentadienyl-. Submitted by D. E. Bublitz, William E. McEwen, and Jacob Kleinberg1. DOI: 10.15227/orgsyn.041.0096. Organic Syntheses
(S)-(−)-1-AMINO-2-METHOXYMETHYLPYRROLIDINE (SAMP) AND (R)-(+)-1-AMINO-2-METHOXYMETHYLPYRROLIDINE (RAMP), VERSATILE CHIRAL AUXILIARIES (1-Pyrrolidinamine, 2-(methoxymethyl)-, (S) 1-Pyrrolidinamine, 2-(methoxymethyl)-, (R)) Preparation of 1-Pyrrolidinamine, 2-(methoxymethyl)-, (S) 1-Pyrrolidinamine, 2-(methoxymethyl)-, (R). Submitted by Dieter Enders, Peter Fey, and Helmut Kipphardt1. DOI: 10.15227/orgsyn.065.0173. Organic Syntheses
(S)-(+)-2,4,6-TRIMETHYLBENZENESULFINAMIDE Preparation of (S)-(+)-2,4,6-TRIMETHYLBENZENESULFINAMIDE. Submitted by Tokala Ramachandar, Yongzhong Wu, Junyi Zhang, and Franklin A. Davis1. DOI: 10.15227/orgsyn.083.0131. Organic Syntheses
(S)-(-)-2-ALLYLCYCLOHEXANONE (2-Allylcyclohexan-1-one) Preparation of 2-Allylcyclohexan-1-one. Submitted by Manfred Braun, Panos Meletis, and Mesut Fidan1. DOI: 10.15227/orgsyn.086.0047. Organic Syntheses
(S)-2-CHLOROALKANOIC ACIDS OF HIGH ENANTIOMERIC PURITY FROM (S)-2-AMINO ACIDS: (S)-2-CHLOROPROPANOIC ACID (Propanoic acid, 2-chloro-, (S)-) Preparation of Propanoic acid, 2-chloro-, (S)-. Submitted by Bernhard Koppenhoefer and Volker Schurig1. DOI: 10.15227/orgsyn.066.0151. Organic Syntheses
(S)-( + )-2-(p-TOLUENESULFINYL)-2-CYCLOPENTENONE: PRECURSOR FOR ENANTIOSELECTIVE SYNTHESIS OF 3-SUBSTITUTED CYCLOPENTANONES (2-Cyclopenten-1-one, 2-[(4-methylphenyl)sulfinyl]-, (S)-) Preparation of 2-Cyclopenten-1-one, 2-[(4-methylphenyl)sulfinyl]-, (S)-. Submitted by Martin Hulce, John P. Mallomo, Leah L. Frye, Timothy P. Kogan, and Gary H. Posner1. DOI: 10.15227/orgsyn.064.0196. Organic Syntheses
(S)-3-(tert-BUTYLOXYCARBONYLAMINO)-4-PHENYLBUTANOIC ACID ([Benzenebutanoic acid, β-[[(1,1-dimethylethoxy)carbonyl]amino]-, (S)-) Preparation of [Benzenebutanoic acid, β-[[(1,1-dimethylethoxy)carbonyl]amino]-, (S)-. Submitted by Michael R. Linder, Steffen Steurer, and Joachim Podlech1. DOI: 10.15227/orgsyn.079.0154. Organic Syntheses
(S)-4-(PHENYLMETHYL)-2-OXAZOLIDINONE (2-Oxazolidinone, 4-(phenylmethyl)-, (S)-) Preparation of 2-Oxazolidinone, 4-(phenylmethyl)-, (S)-. Submitted by James R. Gage and David A. Evans1. DOI: 10.15227/orgsyn.068.0077. Organic Syntheses
S-(−)-5-HEPTYL-2-PYRROLIDINONE. CHIRAL BICYCLIC LACTAMS AS TEMPLATES FOR PYRROLIDINES AND PYRROLIDINONES (2-Pyrrolidinone, 5-heptyl-, (S)-) Preparation of 2-Pyrrolidinone, 5-heptyl-, (S)-. Submitted by M. A. Tschantz, L. E. Burgess, and A. I. Meyers1. DOI: 10.15227/orgsyn.073.0221. Organic Syntheses
(S)-5-PYRROLIDIN-2-YL-1H-TETRAZOLE Preparation of (S)-5-PYRROLIDIN-2-YL-1H-TETRAZOLE. Submitted by Valentina Aureggi1,2, Vilius Franckevicius3, Matthew O. Kitching3, Steven V. Ley3, Deborah A. Longbottom3, Alexander J. Oelke3, and Gott… Organic Syntheses
(S)-8a-METHYL-3,4,8,8a-TETRAHYDRO-1,6(2H, 7H)-NAPHTHALENEDIONE (1,6(2H, 7H)-Naphthalenedione, 3,4,8,8a-tetrahydro-8a-methyl-, (S)-) Preparation of 1,6(2H, 7H)-Naphthalenedione, 3,4,8,8a-tetrahydro-8a-methyl-, (S)-. Submitted by Paul Buchschacher1, A. Fürst1, and J. Gutzwiller1. DOI: 10.15227/orgsyn.063.0037. Organic Syntheses
SAFE AND SCALABLE PREPARATION OF BARLUENGA'S REAGENT (Bis(pyridine)iodonium(I) tetrafluoroborate) Preparation of Bis(pyridine)iodonium(I) tetrafluoroborate. Submitted by Justin M. Chalker, Amber L. Thompson, and Benjamin G. Davis1. DOI: 10.15227/orgsyn.087.0288. Organic Syntheses
SALICYL-o-TOLUIDE (o-Salicylotoluide) Preparation of o-Salicylotoluide. Submitted by C. F. H. Allen and J. VanAllan. DOI: 10.15227/orgsyn.026.0092. Organic Syntheses
(−)-SALSOLIDINE (Isoquinoline, 1,2,3,4-tetrahydro-6,7-dimethoxy-1-methyl-, (S)-) Preparation of Isoquinoline, 1,2,3,4-tetrahydro-6,7-dimethoxy-1-methyl-, (S)-. Submitted by Albert I. Meyers1, Michael Boes, and Daniel A. Dickman. DOI: 10.15227/orgsyn.067.0060. Organic Syntheses
(S)-(−)- AND (R)-(+)-1,1'-BI-2-NAPHTHOL ([1,1'-Binaphthalene]-2,2'-diol, (S)- and [1,1'-Binaphthalene]-2,2'-diol, (R)-) Preparation of [1,1'-Binaphthalene]-2,2'-diol, (S)- and [1,1'-Binaphthalene]-2,2'-diol, (R)-. Submitted by Romas J. Kazlauskas1. DOI: 10.15227/orgsyn.070.0060. Organic Syntheses
(Sa,S)-N-[2´-(4-METHYLPHENYLSULFONAMIDO)-1,1´-BINAPHTHYL-2-YL]PYRROLIDINE-2-CARBOXAMIDE: AN ORGANOCATALYST FOR THE DIRECT ALDOL REACTION Condensation Preparation of (Sa,S)-N-[2´-(4-METHYLPHENYLSULFONAMIDO)-1,1´-BINAPHTHYL-2-YL]PYRROLIDINE-2-CARBOXAMIDE: AN ORGANOCATALYST FOR THE DIRECT ALDOL REACTION. Submitted by Santiago F. Viózquez, 1Gabriela Gu… Organic Syntheses
SCHWARTZ'S REAGENT (Zirconium, chlorobis(η5-2,4-cyclopentadien-1-yl)hydro-) Preparation of Zirconium, chlorobis(η5-2,4-cyclopentadien-1-yl)hydro-. Submitted by Stephen L. Buchwald1, Susan J. LaMaire, Ralph B. Nielsen, Brett T. Watson, and Susan M. King. DOI: 10.15227/orgsyn.0… Organic Syntheses
SEBACIL (1,2-Cyclodecanedione) Preparation of 1,2-Cyclodecanedione. Submitted by A. T. Blomquist and Albert Goldstein1. DOI: 10.15227/orgsyn.036.0077. Organic Syntheses
SEBACOIN (Cyclodecanone, 2-hydroxy-) Preparation of Cyclodecanone, 2-hydroxy-. Submitted by Norman L. Allinger1. DOI: 10.15227/orgsyn.036.0079. Organic Syntheses
SEBACONITRILE AND ω-CYANOPELARGONIC ACID (Sebaconitrile and pelargonic acid, θ-cyano-) Preparation of Sebaconitrile and pelargonic acid, θ-cyano-. Submitted by B. S. Biggs and W. S. Bishop. DOI: 10.15227/orgsyn.025.0095. Organic Syntheses
sec-BUTYL α-n-CAPROYLPROPIONATE (Octanoic acid, 2-methyl-3-oxo-, sec-butyl ester) Preparation of Octanoic acid, 2-methyl-3-oxo-, sec-butyl ester. Submitted by Kenneth L. Rinehart, Jr.1. DOI: 10.15227/orgsyn.035.0015. Organic Syntheses
SECONDARY AND TERTIARY ALKYL KETONES FROM CARBOXYLIC ACID CHLORIDES AND LITHIUM PHENYLTHIO(ALKYL)CUPRATE REAGENTS: tert-BUTYL PHENYL KETONE (1-Propanone, 2,2-dimethyl-1-phenyl) Preparation of 1-Propanone, 2,2-dimethyl-1-phenyl. Submitted by Gary H. Posner1 and Charles E. Whitten. DOI: 10.15227/orgsyn.055.0122. Organic Syntheses
SELECTIVE CYCLOPROPANATION OF (S)-(−)-PERILLYL ALCOHOL: 1-HYDROXYMETHYL-4-(1-METHYLCYCLOPROPYL)-1-CYCLOHEXENE (1-Cyclohexene-1-methanol, 4-(1-methylcyclopropyl)-) Preparation of 1-Cyclohexene-1-methanol, 4-(1-methylcyclopropyl)-. Submitted by Keiji Maruoka, Soichi Sakane, and Hisashi Yamamoto1. DOI: 10.15227/orgsyn.067.0176. Organic Syntheses
SELECTIVE EPOXIDATION OF TERMINAL DOUBLE BONDS: 10,11-EPOXYFARNESYL ACETATE (2,6-Nonadien-1-ol, 9-(3,3-dimethyloxiranyl)-3,7-dimethyl-, acetate, (E,E)-) Oxidation Preparation of 2,6-Nonadien-1-ol, 9-(3,3-dimethyloxiranyl)-3,7-dimethyl-, acetate, (E,E)-. Submitted by R. P. Hanzlik1. DOI: 10.15227/orgsyn.056.0112. Organic Syntheses
SELECTIVE HALOGEN-LITHIUM EXCHANGE REACTIONS OF 2-(2'-HALOPHENYL)ETHYL HALIDES: SYNTHESIS OF 4,5-METHYLENEDIOXYBENZOCYCLOBUTENE AND 1-PHENYL-3,4-DIHYDRO-6,7-METHYLENEDIOXYISOQUINOLINE (Cyclobuta[f]-1,3-benzodioxole, 5,6-dihydro- and 1,3-dioxolo [4,5-g]isoquinoline, 7,8-dihydro-5-phenyl-) Preparation of Cyclobuta[f]-1,3-benzodioxole, 5,6-dihydro- and 1,3-dioxolo [4,5-g]isoquinoline, 7,8-dihydro-5-phenyl-. Submitted by Dennis J. Jakiela, Paul Helquist1, and Lawrence D. Jones2. DOI: 10.1… Organic Syntheses
SELECTIVE HYDROBORATION OF A 1,3,7-TRIENE: HOMOGERANIOL (3,7-Nonadien-1-ol, 4,8-dimethyl-, (E)-) Addition Preparation of 3,7-Nonadien-1-ol, 4,8-dimethyl-, (E)-. Submitted by Eric J. Leopold1. DOI: 10.15227/orgsyn.064.0164. Organic Syntheses
SELECTIVE Pd-CATALYZED AMINATIONS ON CHLORO-IODOPYRIDINES: SYNTHESIS OF ETHYL 4-[(6-CHLOROPYRIDIN-3-YL)AMINO]BENZOATE Preparation of SELECTIVE Pd-CATALYZED AMINATIONS ON CHLORO-IODOPYRIDINES: SYNTHESIS OF ETHYL 4-[(6-CHLOROPYRIDIN-3-YL)AMINO]BENZOATE. Submitted by Geert Rombouts1, Bert U.W. Maes1, Tim H.M. Jonckers2,… Organic Syntheses
SELECTIVE PROTECTION OF 1,3-DIOLS AT THE MORE HINDERED HYDROXY GROUP: 3-(METHOXYMETHOXY)-1-BUTANOL (1-Butanol, 3-(methoxymethoxy)-) Protection Preparation of 1-Butanol, 3-(methoxymethoxy)-. Submitted by William F. Bailey, Matthew W. Carson, and Lyn M. J. Zarcone1. DOI: 10.15227/orgsyn.075.0177. Organic Syntheses
SELECTIVE TRIALKYLATION OF CYCLEN WITH tert-BUTYL BROMOACETATE (1,4,7,10-Tetraazacyclododecane-1,4,7-triacetic acid, Tri-tert-butyl Ester Hydrobromide) Preparation of 1,4,7,10-Tetraazacyclododecane-1,4,7-triacetic acid, Tri-tert-butyl Ester Hydrobromide. Submitted by Dennis A. Moore1. DOI: 10.15227/orgsyn.085.0010. Organic Syntheses
SELECTIVE α-BROMINATION OF AN ARALKYL KETONE WITH PHENYLTRIMETHYLAMMONIUM TRIBROMIDE: 2-BROMOACETYL-6-METHOXYNAPHTHALENE AND 2,2-DIBROMOACETYL-6-METHOXYNAPHTHALENE (Ethanone, 2-bromo-1-(6-methoxy-2-naphthalenyl)- and Ethanone, 2,2-dibromo-1-(6-methoxy-2-naphthalenyl)-) Preparation of Ethanone, 2-bromo-1-(6-methoxy-2-naphthalenyl)- and Ethanone, 2,2-dibromo-1-(6-methoxy-2-naphthalenyl)-. Submitted by J. Jacques and A. Marquet1. DOI: 10.15227/orgsyn.053.0111. Organic Syntheses
SELENOPHENOL (Benzeneselenol) Preparation of Benzeneselenol. Submitted by Duncan G. Foster. DOI: 10.15227/orgsyn.024.0089. Organic Syntheses
SEMICARBAZIDE SULFATE Preparation of SEMICARBAZIDE SULFATE. Submitted by A. W. Ingersoll, L. J. Bircher, and M. M. Brubaker. DOI: 10.15227/orgsyn.005.0093. Organic Syntheses
SILVER-CATALYZED REARRANGEMENT OF PROPARGYLIC SULFINATES: SYNTHESIS OF ALLENIC SULFONES Rearrangement Preparation of SILVER-CATALYZED REARRANGEMENT OF PROPARGYLIC SULFINATES: SYNTHESIS OF ALLENIC SULFONES. Submitted by Michael Harmata, Zhengxin Cai, and Chaofeng Huang1. DOI: 10.15227/orgsyn.088.0309. Organic Syntheses
SILYLATION OF 2-METHYL-2-PROPEN-1-OL DIANION: 2-(HYDROXYMETHYL)ALLYLTRIMETHYLSILANE Preparation of SILYLATION OF 2-METHYL-2-PROPEN-1-OL DIANION: 2-(HYDROXYMETHYL)ALLYLTRIMETHYLSILANE. Submitted by Barry M. Trost, Dominic M. T. Chan, and Thomas N. Nanninga1. DOI: 10.15227/orgsyn.062.0… Organic Syntheses
SILYLATION OF KETONES WITH ETHYL TRIMETHYLSILACETATE: (Z)-3-TRIMETHYLSILOXY-2-PENTENE (Silane, [(1-ethyl-1-propenyl)oxyl]trimethyl-, (Z)-) Preparation of Silane, [(1-ethyl-1-propenyl)oxyl]trimethyl-, (Z)-. Submitted by Isao Kuwajima, Eiichi Nakamura, and Koichi Hashimoto1. DOI: 10.15227/orgsyn.061.0122. Organic Syntheses
Simplified Preparation of Dimethyldioxirane (DMDO) Preparation of Simplified Preparation of Dimethyldioxirane (DMDO). Submitted by Douglass F. Taber1,*, Peter W. DeMatteo and Rasha A. Hassan. DOI: 10.15227/orgsyn.090.0350. Organic Syntheses

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