chempirical
Reaction database

Reactions

3,374 reactions: 10 worked examples with a reagent table you can scale, 503 named reactions and 2,861 checked procedures from Organic Syntheses.

2,905–2,928 of 3,374

  1. Rhodium-Catalyzed Direct Amination of Arene C-H Bonds Using Azides as the Nitrogen Source Org. Synth. Vol. 91, p. 52
  2. Rhodium-catalyzed enantioselective addition of arylboronic acids to in situ generated N-BOC arylimines. Preparation of (S)-tert-butyl (4-chlorophenyl)(thiophen-2-yl)methylcarbamateAddition Org. Synth. Vol. 86, p. 360 · Storgaard and Ellman
  3. Rhodium-catalyzed heterocycloaddition of a diazomalonate and a nitrile: 4-carbomethoxy-5-methoxy-2-phenyl-1,3-oxazoleCycloaddition Org. Synth. Coll. Vol. 9, p. 155; Vol. 74, p. 229 · Tullis and Helquist
  4. D-Ribonolactone and 2,3-isopropylidene(D-ribonolactone) Org. Synth. Vol. 82, p. 75 · Williams et al.
  5. Ricinelaidic acid lactone Org. Synth. Coll. Vol. 7, p. 470; Vol. 63, p. 192 · Thalmann et al.
  6. Ring contraction via a Favorskii-type rearrangement: cycloundecanoneRearrangement Org. Synth. Coll. Vol. 6, p. 368; Vol. 56, p. 107 · Wohllebe and Jr
  7. Ring expansion and cleavage of succinoin derivatives: spiro[4.5]decane-1,4-dione and ethyl 4-cyclohexyl-4-oxobutanoate Org. Synth. Coll. Vol. 8, p. 578; Vol. 65, p. 17 · Nakamura and Kuwajima
  8. Ring-closing metathesis synthesis of N-Boc-3-pyrrolineMetathesis Org. Synth. Vol. 80, p. 85 · Ferguson et al.
  9. (RS)-(+)-2-methyl-2-propanesulfinamide Org. Synth. Vol. 82, p. 157 · Weix and Ellman
  10. Ruthenium-catalyzed alkylation of aromatic ketones with olefins: 8-[2-(triethoxysilyl)ethyl]-1-tetralone Org. Synth. Vol. 80, p. 104 · Kakiuchi and Murai
  11. Ruthenium-catalyzed arylation of ortho C-H bond in an aromatic with an arylboronate: 8-phenyl-1-tetralone Org. Synth. Vol. 87, p. 209 · Kitazawa et al.
  12. Ruthenocene Org. Synth. Coll. Vol. 5, p. 1001; Vol. 41, p. 96 · Bublitz et al.
  13. (Sa,S)-N-[2´-(4-methylphenylsulfonamido)-1,1´-binaphthyl-2-yl]pyrrolidine-2-carboxamide: an organocatalyst for the direct aldol reactionCondensation Org. Synth. Vol. 88, p. 317 · Viózquez et al.
  14. Safe and scalable preparation of barluenga'S reagent Org. Synth. Vol. 87, p. 288 · Chalker et al.
  15. Salicyl-o-toluide Org. Synth. Coll. Vol. 3, p. 765; Vol. 26, p. 92 · Allen and VanAllan
  16. (−)-Salsolidine Org. Synth. Coll. Vol. 8, p. 573; Vol. 67, p. 60 · Meyers et al.
  17. Schwartz'S reagent Org. Synth. Coll. Vol. 9, p. 162; Vol. 71, p. 77 · Buchwald et al.
  18. Sebacil Org. Synth. Coll. Vol. 4, p. 838; Vol. 36, p. 77 · Blomquist and Goldstein
  19. Sebacoin Org. Synth. Coll. Vol. 4, p. 840; Vol. 36, p. 79 · Allinger
  20. Sebaconitrile and ω-cyanopelargonic acid Org. Synth. Coll. Vol. 3, p. 768; Vol. 25, p. 95 · Biggs and Bishop
  21. Secondary and tertiary alkyl ketones from carboxylic acid chlorides and lithium phenylthio(alkyl)cuprate reagents: tert-butyl phenyl ketone Org. Synth. Coll. Vol. 6, p. 248; Vol. 55, p. 122 · Posner and Whitten
  22. anti-Selective boron-mediated asymmetric aldol reaction of carboxylic esters: synthesis of (2S, 3R)-2,4-dimethyl-1,3-pentanediolCondensation Org. Synth. Vol. 79, p. 116 · Abiko
  23. Selective cyclopropanation of (S)-(−)-perillyl alcohol: 1-hydroxymethyl-4-(1-methylcyclopropyl)-1-cyclohexene Org. Synth. Coll. Vol. 8, p. 321; Vol. 67, p. 176 · Maruoka et al.
  24. Selective epoxidation of terminal double bonds: 10,11-epoxyfarnesyl acetateOxidation Org. Synth. Coll. Vol. 6, p. 560; Vol. 56, p. 112 · Hanzlik