(±) trans-3,3'-(1,2-Cyclopropanediyl)bis-2-(E)-propenoic acid, diethyl ester: tandem oxidation procedure (TOP) using MnO2 oxidation-stabilized phosphorane trapping
Organic SynthesesOxidation
A checked procedure from Organic Syntheses, the journal whose preparations are repeated in a second laboratory before publication. The full experimental, with amounts, hazards and characterisation data, is on orgsyn.org.
Reagents
| Compound | Role | Equiv | MW (g/mol) | ρ (g/mL) | Safety |
|---|---|---|---|---|---|
| Trioctylphosphine4731-53-7 · C24H51P | product | — | 370.65 | — | Danger |
More oxidation reactions
- Air Oxidation of Primary Alcohols Catalyzed by Copper(I)/TEMPO. Preparation of 2-Amino-5-bromobenzaldehyde
- Aldehydes by oxidation of terminal olefins with chromyl chloride: 2,4,4-trimethylpentanal
- Aldehydes from primary alcohols by oxidation with chromium trioxide: heptanal
- Allylic Oxidation Catalyzed by Dirhodium(II) Tetrakis[ε-caprolactamate] of tert-Butyldimethylsilyl-protected trans-Dehydroandrosterone
- Allylic oxidation with hydrogen peroxide–selenium dioxide: trans-pinocarveol
- Anodic oxidation of acids: dimethyl decanedioate