Sulfinimines (thiooximine S-oxides): asymmetric synthesis of methyl (R)-(+)-β-phenylalanate from (S)-(+)-N-(benzylidene)-p-toluenesulfinamide

CAS index name: Benzenepropanoic acid, β-amino-, (R)-, methyl ester from Benzenesulfinamide, 4-methyl-N-(phenylmethylene)- [S-(E)]-

Organic Syntheses

Reaction scheme of Sulfinimines (thiooximine S-oxides): asymmetric synthesis of methyl (R)-(+)-β-phenylalanate from (S)-(+)-N-(benzylidene)-p-toluenesulfinamide from Organic Syntheses
Scheme as published in Org. Synth. Vol. 77, p. 50.

A checked procedure from Organic Syntheses, the journal whose preparations are repeated in a second laboratory before publication. The full experimental, with amounts, hazards and characterisation data, is on orgsyn.org.

Reagents

The compound this preparation makes is not in the catalogue, so no reagents or figures are listed here.

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