Dimethyl squarate and its conversion to 3-ethenyl-4-methoxycyclobutene-1,2-dione and 2-butyl-6-ethenyl-5-methoxy-1,4-benzoquinone

CAS index name: 3-Cyclobutene-1,2-dione, 3-ethenyl-4-methoxy- and 2,5-cyclohexadiene-1,4-dione, 5-butyl-3-ethenyl-2-methoxy- from 3-cyclobutene-1,2-dione, 3,4-dimethoxy-

Organic Syntheses

Reaction scheme of Dimethyl squarate and its conversion to 3-ethenyl-4-methoxycyclobutene-1,2-dione and 2-butyl-6-ethenyl-5-methoxy-1,4-benzoquinone from Organic Syntheses
Scheme as published in Org. Synth. Vol. 76, p. 189.

A checked procedure from Organic Syntheses, the journal whose preparations are repeated in a second laboratory before publication. The full experimental, with amounts, hazards and characterisation data, is on orgsyn.org.

Reagents

CompoundRoleEquivMW (g/mol)ρ (g/mL)Safety
3,4-Dimethoxy-3-cyclobutene-1,2-dione5222-73-1 · C6H6O4 product — 142.11 — Irritant (GHS07)Health Hazard (GHS08)Danger

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