1,4-Functionalization of 1,3-dienes via palladium-catalyzed chloroacetoxylation and allylic amination: 1-acetoxy-4-diethylamino-2-butene and 1-acetoxy-4-benzylamino-2-butene

CAS index name: 2-Buten-1-ol, 4-(diethylamino)-, acetate ester and 2-Buten-1-ol, 4-[(phenylmethyl)amino]-, acetate ester

Organic Syntheses

Reaction scheme of 1,4-Functionalization of 1,3-dienes via palladium-catalyzed chloroacetoxylation and allylic amination: 1-acetoxy-4-diethylamino-2-butene and 1-acetoxy-4-benzylamino-2-butene from Organic Syntheses
Scheme as published in Org. Synth. Coll. Vol. 8, p. 9; Vol. 67, p. 105.

A checked procedure from Organic Syntheses, the journal whose preparations are repeated in a second laboratory before publication. The full experimental, with amounts, hazards and characterisation data, is on orgsyn.org.

Reagents

The compound this preparation makes is not in the catalogue, so no reagents or figures are listed here.

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