Binap
Properties
- Molecular formula
- C44H32P2
- Molar mass
- 622.69 g/mol
- Exact mass
- 622.1979 Da
- logP
- 9.18Crippen estimate
- Polar surface area
- 0.0 Ų
- H-bond donors / acceptors
- 0 / 0
- Rotatable bonds
- 7
Hazards
Warning
- H315 Causes skin irritation96% of notifiers
- H319 Causes serious eye irritation96% of notifiers
- H335 May cause respiratory irritation96% of notifiers
Aggregated from 25 ECHA notifications, via PubChem; a share says how many notifiers assign that statement.
Precautionary statements
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P501
Identifiers
CAS number
76189-55-4SMILES
c1ccc(P(c2ccccc2)c2ccc3ccccc3c2-c2c(P(c3ccccc3)c3ccccc3)ccc3ccccc23)cc1InChIKey
MUALRAIOVNYAIW-UHFFFAOYSA-NInChI
InChI=1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32HWeigh it out
Type any one amount. The others follow from the molar mass.
Names and synonyms
14 names · show all
- Phosphine, 1,1′-[(1R)-[1,1′-binaphthalene]-2,2′-diyl]bis[1,1-diphenyl-
- Phosphine, [1,1′-binaphthalene]-2,2′-diylbis[diphenyl-, (R)-
- Phosphine, (1R)-[1,1′-binaphthalene]-2,2′-diylbis[diphenyl-
- 1,1′-[(1R)-[1,1′-Binaphthalene]-2,2′-diyl]bis[1,1-diphenylphosphine]
- (+)-BINAP
- (R)-Bis(diphenylphosphino)-1,1′-binaphthyl
- (R)-BINAP
- (R)-(+)-BINAP
- (R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl
- (R)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl
- (+)-(1R)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine]
- (1R)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine]
- (R)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene
- Binap, (A+-)-
Reactions
- Discussion Addendum for: Resolution of 1,1'-bi-2-naphthol; (R)-(+)- and (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (BINAP)product
- (R)-(+)- AND (S)-(−)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP) (Phosphine, [1,1'-binaphthalene]-2,2'-diylbis[diphenyl-, (R)- and (S))product
- (R)-(+)- AND (S)-(−)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP) (Phosphine, [1,1'-binaphthalene]-2,2'-diylbis[diphenyl-, (R)- or (S)-)product
Work with Binap
Stereoisomers, salts and isotopologues
The same compound in another form: other stereochemistry, a salt or hydrate, the free acid or base, or an isotope-labelled version.
((R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)palladium(II) chloride127593-28-6Salt
((R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)palladium(II) chloride115826-95-4Salt
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II)134524-84-8Salt
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium (II)132071-87-5Salt
(-)-BINAP76189-56-5
BINAP98327-87-8
Similar compounds
(R)-2-Diphenyphosphino-2'-hydroxyl-1,1'-binaphthyl149917-88-477 % similar
(S)-(-)-2,2'-Bis(di-P-tolylphosphino)-1,1'-binaphthyl100165-88-671 % similar
(R)-(+)-2,2'-Bis(di-P-tolylphosphino)-1,1'-binaphthyl99646-28-371 % similar
(2'-Methoxy-1,1'-binaphthalen-2-yl)(diphenyl)phosphine134484-36-971 % similar
(R)-Mop145964-33-671 % similar
(R)-(+)-2,2'-Bis(di(3,5-xylyl)phosphino)-1,1'-binaphthyl135139-00-364 % similar
(R)-Dm-binap137219-86-464 % similar
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)261948-85-062 % similar
Tanimoto similarity of circular fingerprints over the whole catalogue. All similar compounds