Formic acid

CH2O2CAS 64-18-646.02 g/mol

OOH
Carboxylic acid

Properties

Molecular formula
CH2O2
Molar mass
46.02 g/mol
Exact mass
46.0055 Da
Density
1.22 g/mL (at 20 °C)
Melting point
8.4 °C
Boiling point
100.5 °C
pKa
3.75 (20 °C)
Flash point
68.9 °C (closed cup)
Water solubility
miscible
logP
-0.30Crippen estimate
Polar surface area
37.3 Ų
H-bond donors / acceptors
1 / 1
Rotatable bonds
0

Hazards

Danger
Flammable (GHS02)Corrosive (GHS05)Acute Toxic (GHS06)

Harmonised EU classification (CLP Annex VI, index 607-001-00-0), via PubChem.

Precautionary statements

P210, P233, P234, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P370+P378, P390, P403+P233, P403+P235, P405, P406, P501

Identifiers

CAS number
64-18-6
SMILES
O=CO
InChIKey
BDAGIHXWWSANSR-UHFFFAOYSA-N
InChI
InChI=1S/CH2O2/c2-1-3/h1H,(H,2,3)

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Names and synonyms

19 names · show all
  • Aminic acid
  • Formylic acid
  • Hydrogen carboxylic acid
  • Methanoic acid
  • Bilorin
  • Collo-bueglatt
  • Collo-didax
  • Formisoton
  • Myrmicyl
  • Formira
  • Add-F
  • Methanoic acid monomer
  • Ameisensaure
  • Sybest
  • Wonderbond hardener M 600L
  • Ensilox
  • Amasil
  • Amasil 85
  • Add-F (silage additive)

Safety data sheets

One stored sheet lists this compound in section 3, matched by the CAS number 64-18-6. Each row opens the sheet with its composition and PDF.

Work with Formic acid

Stereoisomers, salts and isotopologues

The same compound in another form: other stereochemistry, a salt or hydrate, the free acid or base, or an isotope-labelled version.

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